Inorganica Chimica Acta p. 101 - 103 (1996)
Update date:2022-07-29
Topics:
Costello, Michael T.
Harris, Terri A.
Walton, Richard A.
The mixed phosphine-arsine ligand Ph2PCH2CH2AsPh2 (arphos) has been used to stabilize the rhenium polyhydrides Re2H8(arphos)2 and ReH7 (arphos). The heptahydride is the first example of a compound of the type ReH7L2 which contains a mixed phosphine-arsine donor set. The spectroscopic and electrochemical properties and stabilities of these complexes are described and compared with data for other complexes of the types Re2H8L4 and ReH7L2.
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