121060-00-2

Upstream product

• 17253-10-0 2-(2,3-dihydrobenzo[b][1,4]dioxin-6-yl)acetonitrile 
• 108-46-3 recorcinol 

Downstream Products

• 96754-91-5 3-(2,3-dihydro-1,4-benzodioxin-6-yl)-7-hydroxyisoflavone 
• 163130-43-6 2-(2,3-Dihydro-benzo[1,4]dioxin-6-yl)-1-(2-hydroxy-4-methoxy-phenyl)-ethanone 
• 121060-03-5 Acetic acid (2S,3R,4S,5R,6R)-4,5-diacetoxy-6-acetoxymethyl-2-[4-(2-2,3-dihydro-benzo[1,4]dioxin-6-yl-acetyl)-3-hydroxy-phenoxy]-tetrahydro-pyran-3-yl ester 

Relevant academic research and scientific papers

SYNTHETIC AND MODIFIED ISOFLAVONOIDS. III. SYNTHESIS OF BENZODIOXANE ANALOGUES OF PSEUDOBAPTIGENIN

Benzodioxane analogues of pseudobaptigenin with alkyl fragments in positions 2 and 6 of the chromone ring have been synthesized from α-(1,4-benzodioxan-6-yl)-2-hydroxy-6-alkylacetophenones.

EFFECTIVE SYNTHESIS OF 7-HYDROXYISOFLAVONE O-GLUCOSIDES

An effective procedure for condensing acetobromoglucose with 2,4-dihydroxy phenyl benzyl ketones has been developed.The 2-hydroxy-4-(β-D-tetra-O-acetylglucopyranosyloxy)phenyl benzyl ketones synthesized with yields of 47-69percent have been converted under the action of ethyl orthoformate in pyridine solution into 7-hydroxyisoflavone O-glukosides and these have also been obtained by the glycosylation of 7-hydroxyisoflavone.The advantages and disadvantages of the alternative pathways of the synthesis of 7-hydroxyisoflavone O-glykosides are discussed.