121077-72-3Relevant academic research and scientific papers
Facile aluminum(III) chloride catalyzed preparation of β,γ-unsaturated O-aryl esters from allylsilanes and aryl chloroformates
Olah,Van Vliet,Wang,Prakash
, p. 159 - 161 (2007/10/02)
The aluminum trichloride catalyzed reaction of phenyl chloroformate (1a) with allylsilanes 2a-e gives phenyl 3-alkenoates in excellent yields. The reaction with allyltrimethylsilane 2a also works with a number of para substituted aryl chloroformates 1b-f.
Synthesis of β,γ-Unsaturated Carboxylic Acid Esters via Aryloxycarbonylation of Allylsilanes
Mayr, Herbert,Cambanis, Anton,Baeuml, Englbert
, p. 962 - 963 (2007/10/02)
The β,γ-unsaturated carboxylic acid 4-chlorophenyl esters 3a-e are synthesized from the allylsilanes 2a-e and dichlorobis(4-chlorophenoxy)methane (1) in the presence of 1.1 equivalents of tin(IV) chloride.
