1210872-30-2Relevant academic research and scientific papers
Rh(III)-Catalyzed Distal C-H Alkenylation of Weakly Coordinating Acetamides Via Desilylation Pathway
Ramesh, Vinay Bapu,Muniraj, Nachimuthu,Prabhu, Kandikere Ramaiah
, p. 3683 - 3688 (2019)
Rh(III)-Catalyzed distal ortho-C?H alkenylation of arylacetamides have been reported employing acetamide, a weak coordinating group, as a directing group. This challenging C?H alkenylation of arylacetamides has been achieved by using arylalkynyl silanes as a surrogate for terminal alkynes under redox neutral process through desilylation pathway. The control experiments suggest that the in situ generatedRh-species is likely to be Lewis acidic, which is playing a vital role in the desilylation step. (Figure presented.).
Oxidative C-H homodimerization of phenylacetamides
Pintori, Didier G.,Greaney, Michael F.
supporting information; experimental part, p. 5713 - 5715 (2011/12/04)
A range of secondary and tertiary phenylacetamides undergo oxidative homodimerization to afford biaryls. The reaction proceeds under palladium catalysis in the presence of a copper cocatalyst and oxygen and is most effective for electron-rich substrates.
