121089-65-4Relevant academic research and scientific papers
New Approach to C-Aryl Glycosides Starting from Phenol and Glycosyl Fluoride. Lewis Acid-Catalyzed Rearrangement of O-Glycoside to C-Glycoside
Matsumoto, Takashy,Katsuki, Miyoko,Suzuki, Keisuke
, p. 6935 - 6938 (1988)
C-Glycosidation of phenols is achieved by treatment of glycosyl fluoride with phenolic compound under Lewis acidic conditions, wich leads to initial O-glycoside formation followed by rearrangement to C-congener.Cp2HfCl2-AgClO4 is particularly effective for this conversion.
