Tetrahedron Letters p. 6935 - 6938 (1988)
Update date:2022-07-29
Topics:
Matsumoto, Takashy
Katsuki, Miyoko
Suzuki, Keisuke
C-Glycosidation of phenols is achieved by treatment of glycosyl fluoride with phenolic compound under Lewis acidic conditions, wich leads to initial O-glycoside formation followed by rearrangement to C-congener.Cp2HfCl2-AgClO4 is particularly effective for this conversion.
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