Tetrahedron Letters p. 6935 - 6938 (1988)
Update date:2022-07-29
Topics:
Matsumoto, Takashy
Katsuki, Miyoko
Suzuki, Keisuke
C-Glycosidation of phenols is achieved by treatment of glycosyl fluoride with phenolic compound under Lewis acidic conditions, wich leads to initial O-glycoside formation followed by rearrangement to C-congener.Cp2HfCl2-AgClO4 is particularly effective for this conversion.
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Doi:10.1021/ja00197a064
(1989)Doi:10.1016/j.tet.2014.12.099
(2015)Doi:10.1002/anie.201705521
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(2016)Doi:10.1007/s11172-009-0262-5
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