12130-88-0 Usage
Description
Pentamethylcyclopentadienylrhenium tricarbonyl is a chemical compound characterized by a rhenium metal center coordinated to three carbon monoxide ligands and a pentamethylcyclopentadienyl ligand. It is a bright yellow crystalline solid that is soluble in non-polar solvents such as toluene and benzene. PENTAMETHYLCYCLOPENTADIENYLRHENIUM TRICARBONYL is distinguished by its unique structure and reactivity, making it a valuable asset in the development of new chemical compounds and materials.
Uses
Used in Organic Synthesis:
Pentamethylcyclopentadienylrhenium tricarbonyl is used as a catalyst for various organic synthesis reactions, facilitating the reduction of double bonds and the formation of carbon-carbon bonds. Its catalytic properties are instrumental in the synthesis of complex organic molecules, contributing to the advancement of organic chemistry.
Used in Organometallic Chemistry:
In the field of organometallic chemistry, Pentamethylcyclopentadienylrhenium tricarbonyl is utilized as a precursor or intermediate in the synthesis of other organometallic compounds. Its unique structure allows for the exploration of new reactions and the development of novel organometallic materials.
Used in Inorganic Chemistry:
Pentamethylcyclopentadienylrhenium tricarbonyl also finds applications in inorganic chemistry, where it is employed in the preparation of inorganic complexes and materials. Its potential use in this field is driven by the compound's ability to form stable coordination compounds with various inorganic ligands.
Used in Catalyst Development:
PENTAMETHYLCYCLOPENTADIENYLRHENIUM TRICARBONYL is used as a catalyst in the development of new chemical processes, where its reactivity and stability contribute to the efficiency and selectivity of the reactions. Its role in catalyst development is crucial for the creation of more sustainable and efficient chemical production methods.
Used in Research and Development:
Pentamethylcyclopentadienylrhenium tricarbonyl is utilized in research and development settings to explore its properties and potential applications further. Its unique characteristics make it an interesting subject for studies in organometallic and inorganic chemistry, potentially leading to new discoveries and applications.
Check Digit Verification of cas no
The CAS Registry Mumber 12130-88-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,2,1,3 and 0 respectively; the second part has 2 digits, 8 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 12130-88:
(7*1)+(6*2)+(5*1)+(4*3)+(3*0)+(2*8)+(1*8)=60
60 % 10 = 0
So 12130-88-0 is a valid CAS Registry Number.
InChI:InChI=1/C10H15.3CO.Re/c1-6-7(2)9(4)10(5)8(6)3;3*1-2;/h1-5H3;;;;
12130-88-0Relevant articles and documents
Reactions of cationic complex [(η5-C5Me5)Re(CO)3I]+ with primary amines leading to cyclic carbamoyl complexes
Aballay, Alvaro,Buono-Core, Gonzalo E.,Godoy, Fernando,Klahn, A. Hugo,Iba?ez, Andrés,Garland, María Teresa
, p. 3749 - 3752 (2010/02/28)
The reaction of cationic complex [(5-C5Me5)Re(CO)3I]+ with aliphatic and aromatic primary amines unexpectedly produced the chelated carbamoyl species trans-(5:1-C5Me4CH2NRC({double bond, long}O))Re(CO)2(I) (1, R = Me; 2, R = Pr; 3, R = Ph; 4, R = p-tolyl). The 1-coordination of carbamoyl moiety linkages to a methylene group of tetramethylcyclopentadienyl ligand was confirmed by X-ray crystallography of complex 3. All the complexes were isolated as pure samples and fully characterized by IR, 1H and 13C NMR spectroscopies, mass spectrometry and elemental analysis.
An investigation into the reactivity of organometallic noble gas complexes: A time-resolved infrared study in supercritical noble gas and alkane solution at room temperature
Grills, David C.,Sun, Xue Z.,Childs, Gavin I.,George, Michael W.
, p. 4300 - 4307 (2007/10/03)
A study investigated the effect of cyclopentadienyl ring substituents on the reactivity of the Group 7 half-sandwich complexes, (η5-C5R5)M(CO)2L (M = Mn and Re; R = H, Me and Et (Mn only); L = Kr and Xe) toward CO in supercritical fluid solution at room temperature. The steric bulk of the three types of ring substituent steadily increased in the order H 5-C5R'5)Mn(CO)2Xe (R' = H and Me) and (η5-C5R'5)Mn(CO)2Kr had very similar reactivity toward CO, while (η5C5Et5)Mn(CO)2L (L = Xe and Kr) were approximately twice as reactive. Experiments with the manganese xenon complexes suggested that the noble gas complexes react with CO in supercritical solution via a dissociative mechanism. This reaction mechanism was further evidenced by temperature dependence studies where the enthalpies of activation were calculated for these noble gas complexes and the analogous alkane complexes.
A novel coordinated inorganic benzene: Synthesis and characterization of {η5-C5Me5Re}2{μ-η6:η6-B4H4CO2(CO)5} [24]
Ghosh, Sundargopal,Shang, Maoyu,Fehlner, Thomas P.
, p. 7451 - 7452 (2007/10/03)
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