1213263-96-7Relevant academic research and scientific papers
Total synthesis of (+)-cacospongionolide B
Oshida, Motoko,Ono, Misaki,Nakazaki, Atsuo,Kobayashi, Susumu
, p. 313 - 328 (2010)
Total synthesis of (+)-cacospongionolide B was achieved. The synthesis involved highly stereoselective C-glycosidation of a glycal derived from D-arabinose with 3-furyl boronic acid in the presence of a palladium catalyst and S-alkyl Suzuki-Miyaura coupling of in situ generated alkylborane prepared by the reaction of vinyl trans-decaMn with alkenyl triflate.
