121328-65-2Relevant articles and documents
Efficient synthesis of rare sugar D-allal via reversal of diastereoselection in the reduction of protected 1,5-anhydrohex-1-en-3-uloses: Protecting group dependence of the stereoselection
Fujiwara, Takashi,Hayashi, Masahiko
scheme or table, p. 9161 - 9163 (2009/04/04)
(Chemical Equation Presented) D-Allal was selectively obtained by reducing bulky-silyl-protected 1,5-anhydrohex-1-en-3-uloses using the NaBH4 - CeCl3·7H2O system. The crucial point of this synthesis is the nature of the pr