121359-48-6

Basic information

• Product Name: 2-(TRIBUTYLSTANNYL)THIAZOLE
• Synonyms: 2-(TRIBUTYLSTANNYL)THIAZOLE;2-(Tributylstannyl)-1,3-thiazole;2-(Tri-n-butylstannyl)thiazole, 96%;2-(Tributylstannyl)-1,3-thiazole 95+%;2-Tributylstaylthiazole;(1,3-Thiazol-2-yl)tributylstannane;Thiazole,2-(tributylstannyl)-;2-(Tributyltin)thiazole
• CAS NO: 121359-48-6
• Molecular Formula: C₁₅H₂₉NSSn
• Molecular Weight: 374.17
• Product Categories: Organostannes;Thiazole;Tributylstanny;Organometallic Reagents;Organotin;Organotins;Chemical Synthesis;Organometallic Reagents
• Mol File: 121359-48-6.mol
• Article Data: 13

Chemical Properties

• Melting Point: 224-225℃
• Boiling Point: 307-309 °C(lit.)
• Flash Point: >230 °F
• Appearance: /
• Density: 1.1900 g/mL at 25 °C(lit.)
• Vapor Pressure: 4.23E-05mmHg at 25°C
• Refractive Index: n20/D 1.5200(lit.)
• Storage Temp.: Keep Cold
• Solubility: Not miscible or difficult to mix.
• PKA: 2.73±0.10(Predicted)
• CAS DataBase Reference: 2-(TRIBUTYLSTANNYL)THIAZOLE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(TRIBUTYLSTANNYL)THIAZOLE(121359-48-6)
• EPA Substance Registry System: 2-(TRIBUTYLSTANNYL)THIAZOLE(121359-48-6)

Safety Data

• Hazard Codes: T,N,Xi
• Statements: 21-25-36/38-48/23/25-50/53
• Safety Statements: 35-36/37/39-45-60-61
• RIDADR: UN 2788 6.1/PG 2
• WGK Germany: 3
• HazardClass: IRRITANT, KEEP COLD, TOXIC
• Hazardous Substances Data: 121359-48-6(Hazardous Substances Data)

Usage

Uses

Different sources of media describe the Uses of 121359-48-6 differently. You can refer to the following data:
1. Reagent for arylation of thiazole by Stille cross-coupling.1
2. Used as reagent for arylation of thiazole by Stille cross-coupling.
3. Reagent for arylation of thiazole by Stille cross-coupling.

InChI:InChI=1/3C4H9.C3H2NS.Sn/c3*1-3-4-2;1-2-5-3-4-1;/h3*1,3-4H2,2H3;1-2H;/rC15H29NSSn/c1-4-7-12-18(13-8-5-2,14-9-6-3)15-16-10-11-17-15/h10-11H,4-9,12-14H2,1-3H3

Upstream product

• 1461-22-9 tributyltin chloride 
• 79265-30-8 2-(trimethylsilyl)thiazole 
• 3034-53-5 2-bromo-1,3-thiazole 

Downstream Products

• 121359-54-4 C₂₄H₂₂N₂OS 
• 121359-58-8 C₂₇H₂₆N₂OS 
• 119952-14-6 C₂₄H₂₅NO 
• 119952-15-7 C₂₄H₂₅NO 
• 808135-10-6 1-[(tert-butyldimethylsilyl)oxy]-1-[5-(2-thiazolyl)oxazol-2-yl]-7-phenylheptane 
• 923946-90-1 2-(thiazol-2-yl)aniline 
• 943925-53-9 3-benzyloxycarbonylamino-5-thiazol-2-yl-benzoic acid methyl ester 
• 676490-68-9 1-[4-(1-phenyl-1-(thiazol-2-yl)-methylene)-piperidin-1-yl]-2-(4,7-dimethoxy-6-azaindol-3-yl)-ethane-1,2-dione 
• 676491-18-2 4-(1-Phenyl-1-(thiazol-2-yl)-methylene)-piperidine-1-carboxylic Acid tert-butyl Ester 
• 672324-84-4 4-(thiazol-2-yl)benzonitrile 
• 1160683-12-4 Ethyl N-{[6-hydroxy-3-phenyl-7-(1,3-thiazol-2-yl)-5-quinoxalinyl]carbonyl}glycinate 
• 1160683-14-6 Ethyl N-{[3-(3,4-difluorophenyl)-6-hydroxy-7-(1,3-thiazol-2-yl)-5-quinoxalinyl]carbonyl}glycinate 
• 1160685-37-9 methyl 6-(methyloxy)-3-phenyl-2-(1,3-thiazol-2-yl)-5-quinoxalinecarboxylate 

Relevant articles and documents

Morphology Driven by Molecular Structure of Thiazole-Based Polymers for Use in Field-Effect Transistors and Solar Cells

The effects of the molecular structure of thiazole-based polymers on the active layer morphologies and performances of electronic and photovoltaic devices were studied. Thus, thiazole-based conjugated polymers with a novel thiazole-vinylene-thiazole (TzVTz) structure were designed and synthesized. The TzVTz structure was introduced to extend the π conjugation and coplanarity of the polymer chains. By combining alkylthienyl-substituted benzo[1,2-b:4,5-b′]dithiophene (BDT) or dithieno[2,3-d:2′,3′-d′]benzo[1,2-b:4,5-b′]dithiophene (DTBDT) electron-donating units and a TzVTz electron-accepting unit, enhanced intermolecular interactions and charge transport were obtained in the novel polymers BDT-TzVTz and DTBDT-TzVTz. With a view to using the polymers in transistor and photovoltaic applications, the molecular self-assembly in and their nanoscale morphologies of the active layers were controlled by thermal annealing to enhance the molecular packing and by introducing a diphenyl ether solvent additive to improve the miscibility between polymer donors and [6,6]phenyl-C71-butyric acid methyl ester (PC71BM) acceptors, respectively. The morphological characterization of the photoactive layers showed that a higher degree of π-electron delocalization and more favorable molecular packing in DTBDT-TzVTz compared with in BDT-TzVTz leads to distinctly higher performances in transistor and photovoltaic devices. The superior performance of a photovoltaic device incorporating DTBDT-TzVTz was achieved through the superior miscibility of DTBDT-TzVTz with PC71BM and the improved crystallinity of DTBDT-TzVTz in the nanofibrillar structure.

DYE, AND PHOTOELECTRIC CONVERSION ELEMENT AND PHOTOELECTROCHEMICAL CELL USING THE SAME

PROBLEM TO BE SOLVED: To provide a photoelectric conversion element and photoelectrochemical cell that achieves a high photoelectric conversion efficiency and in addition that has excellent durability, as well as to provide a dye used therein. SOLUTION: Provided is a dye represented by formula: MLt2L1. (M is ruthenium, osmium, iron, rhenium or technetium; Lt2 is a tridentate ligand represented by the formula (2-2); and L1 is a tridentate ligand of bis-pyrazole-substituted pyridine compound.). (R1 and R2 is -COOH or the like, La is a single bond or an arylene group; n1 is an integer of 1 to 3; n2 is an integer of 1 to 4; R6 is a substituent containing a C1 to 30 alkyl group or the like; and n6 is an integer of 1 to 5.). SELECTED DRAWING: Figure 1 COPYRIGHT: (C)2016,JPOandINPIT

p27 PROTEIN INDUCER

The present invention provides a p27 protein inducing agent comprising a compound represented by general formula (11) below or pharmaceutically acceptable salt thereof as an active ingredient: wherein G 1 , G 2 , G 3 and G 8 are each independently selected from -N= etc., Ring G 6 is selected from divalent aryl etc., A is selected from amino etc., G 4 is selected from oxygen etc., G 5 is selected from oxygen etc., G 7 is selected from -CH 2 - etc., and R 2 is selected from C 1-6 alkyl etc.