121402-01-5

Basic information

• Product Name: (E)-2-(Dimethoxy-phosphoryl)-6-methyl-8-(2,6,6-trimethyl-cyclohex-1-enyl)-oct-5-enoic acid benzyl ester
• Synonyms: (E)-2-(Dimethoxy-phosphoryl)-6-methyl-8-(2,6,6-trimethyl-cyclohex-1-enyl)-oct-5-enoic acid benzyl ester
• CAS NO: 121402-01-5
• Molecular Weight: 476.593
• Mol File: 121402-01-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-2-(Dimethoxy-phosphoryl)-6-methyl-8-(2,6,6-trimethyl-cyclohex-1-enyl)-oct-5-enoic acid benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-2-(Dimethoxy-phosphoryl)-6-methyl-8-(2,6,6-trimethyl-cyclohex-1-enyl)-oct-5-enoic acid benzyl ester(121402-01-5)
• EPA Substance Registry System: (E)-2-(Dimethoxy-phosphoryl)-6-methyl-8-(2,6,6-trimethyl-cyclohex-1-enyl)-oct-5-enoic acid benzyl ester(121402-01-5)

Safety Data

• Hazardous Substances Data: 121402-01-5(Hazardous Substances Data)

Upstream product

• 57443-18-2 benzyl 2-(dimethoxyphosphoryl)acetate 
• 110202-09-0 1-bromo-4-methyl-6-(2,6,6-trimethylcyclohex-1-enyl)-3-hexene 
• 110202-07-8 (E)-4-Methyl-6-(2',6',6'-trimethyl-1'-cyclohexenyl)hex-3-en-1-ol 
• 121402-00-4 (E)-1,3,3-trimethyl-2-(3'-methylhexa-3',5'-dien-1-yl)cyclohex-1-ene 
• 17283-81-7 4-(2,6,6-Trimethyl-cyclohex-1-enyl)-butan-2-on 

Downstream Products

• 121402-02-6 (E)-2-[(S)-3-(tert-Butyl-dimethyl-silanyloxy)-3-(5-oxo-2,5-dihydro-furan-3-yl)-prop-(E)-ylidene]-6-methyl-8-(trimethyl-cyclohex-1-enyl)-oct-5-enoic acid benzyl ester 
• 121402-08-2 (E)-2-[(S)-3-(tert-Butyl-dimethyl-silanyloxy)-3-(5-oxo-2,5-dihydro-furan-3-yl)-prop-(E)-ylidene]-6-methyl-8-(trimethyl-cyclohex-1-enyl)-oct-5-enoic acid benzyl ester 
• 121401-93-2 4S-manoalide diol 
• 121402-04-8 C₃₄H₅₄O₇Si 
• 121402-03-7 (E)-2-[(S)-3-(tert-Butyl-dimethyl-silanyloxy)-3-(5-oxo-2,5-dihydro-furan-3-yl)-prop-(Z)-ylidene]-6-methyl-8-(trimethyl-cyclohex-1-enyl)-oct-5-enoic acid 
• 121402-05-9 4-[(3Z,7E)-(S)-1-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxymethyl-8-methyl-10-(2,6,6-trimethyl-cyclohex-1-enyl)-deca-3,7-dienyl]-5H-furan-2-one 

Relevant articles and documents

SYNTHESIS OF (S)-MANOALIDE DIOL AND THE ABSOLUTE CONFIGURATION OF NATURAL MANOALIDE

A synthesis of (S)-manoalide diol (2a) has been achieved using 2-deoxy-D-ribose as starting material to unequivocally supply the stereochemistry.Reduction of natural manoalide afforded enantiomeric manoalide diol 2b.Thus, the absolute configuration of man