121402-08-2

Upstream product

• 110202-09-0 1-bromo-4-methyl-6-(2,6,6-trimethylcyclohex-1-enyl)-3-hexene 
• 110202-07-8 (E)-4-Methyl-6-(2',6',6'-trimethyl-1'-cyclohexenyl)hex-3-en-1-ol 
• 121401-98-7 (E)-(S)-4-(tert-Butyl-dimethyl-silanyloxy)-3-(tert-butyl-dimethyl-silanyloxymethyl)-6,6-bis-ethylsulfanyl-hex-2-enoic acid ethyl ester 
• 121429-40-1 4-[(S)-1-(tert-Butyl-dimethyl-silanyloxy)-3,3-bis-ethylsulfanyl-propyl]-5H-furan-2-one 
• 121401-97-6 (S)-1,3-Bis-(tert-butyl-dimethyl-silanyloxy)-5,5-bis-ethylsulfanyl-pentan-2-one 
• 121402-00-4 (E)-1,3,3-trimethyl-2-(3'-methylhexa-3',5'-dien-1-yl)cyclohex-1-ene 
• 17283-81-7 4-(2,6,6-Trimethyl-cyclohex-1-enyl)-butan-2-on 
• 121401-99-8 (S)-3-(tert-Butyl-dimethyl-silanyloxy)-3-(5-oxo-2,5-dihydro-furan-3-yl)-propionaldehyde 
• 121402-01-5 (E)-2-(Dimethoxy-phosphoryl)-6-methyl-8-(2,6,6-trimethyl-cyclohex-1-enyl)-oct-5-enoic acid benzyl ester 

Downstream Products

• 121401-93-2 4S-manoalide diol 
• 121402-04-8 C₃₄H₅₄O₇Si 
• 121402-05-9 4-[(3Z,7E)-(S)-1-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxymethyl-8-methyl-10-(2,6,6-trimethyl-cyclohex-1-enyl)-deca-3,7-dienyl]-5H-furan-2-one 
• 121402-03-7 (E)-2-[(S)-3-(tert-Butyl-dimethyl-silanyloxy)-3-(5-oxo-2,5-dihydro-furan-3-yl)-prop-(Z)-ylidene]-6-methyl-8-(trimethyl-cyclohex-1-enyl)-oct-5-enoic acid 

Relevant academic research and scientific papers

SYNTHESIS OF (S)-MANOALIDE DIOL AND THE ABSOLUTE CONFIGURATION OF NATURAL MANOALIDE

A synthesis of (S)-manoalide diol (2a) has been achieved using 2-deoxy-D-ribose as starting material to unequivocally supply the stereochemistry.Reduction of natural manoalide afforded enantiomeric manoalide diol 2b.Thus, the absolute configuration of man