121408-34-2Relevant academic research and scientific papers
Rearrangement of Imidoyl Nitrates to N-Nitro Amides: an Intramolecular O-to-N Migration of a Nitro Group
Carvalho, Emilia,Iley, Jim,Rosa, Eduarda
, p. 1249 - 1250 (1988)
Imidoyl nitrates, formed by the reaction of imidoyl chlorides with AgNO3, rearrange via a unimolecular, intramolecular mechanism probably involving homolytic fission of the O-N bond to yield N-nitro amides; migration of the nitro group in N-arylimidoyl nitrates to the ortho- and para-positions of the N-aryl ring does not involve a special ortho-directing effect.
