Journal of the Chemical Society. Chemical communications p. 1249 - 1250 (1988)
Update date:2022-07-29
Topics:
Carvalho, Emilia
Iley, Jim
Rosa, Eduarda
Imidoyl nitrates, formed by the reaction of imidoyl chlorides with AgNO3, rearrange via a unimolecular, intramolecular mechanism probably involving homolytic fission of the O-N bond to yield N-nitro amides; migration of the nitro group in N-arylimidoyl nitrates to the ortho- and para-positions of the N-aryl ring does not involve a special ortho-directing effect.
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