121408-84-2

Upstream product

• 67-56-1 methanol 
• 110418-31-0 (1R,2S,3R,4R,5S)-5-Benzyloxy-1,2-epoxy-4-hydroxy-3-methylhexyl N,N-diisopropylcarbamate 
• 54783-72-1 ethyl (S)-2-(benzyloxy)propionate 
• 81445-44-5 (S)-2-(benzyloxy)propanal 
• 110418-30-9 (1Z,3R,4R,5S)-5-Benzyloxy-4-hydroxy-3-methyl-1-hexenyl N,N-diisopropylcarbamate 

Relevant academic research and scientific papers

Enantiomerically Pure 2-(Carbamoyloxy)oxiranes and Their Utility in the Synthesis od D- and L-3,6-Dideoxy-3-C-methylhexofuranosides via the Homoaldol Reaction

As an example of a novel flexible strategy in the rapid enantioselective construction of branched carbohydrate analogues by the homoaldol reaction, the title compounds were synthesized. α-Metalated (E)-2-butenyl N,N-diisopropylcarbamate is added to (S)- or (R)-2-benzyloxypropanal.The homoaldol adducts are epoxidized; methanolysis affords furanosides of branched 3,6-dideoxyaldohexoses, or, hydrolysis yields the furanoses.