121408-92-2

Upstream product

• 118759-57-2 (1Z,3R,4R,5R)-5-Benzyloxy-4-hydroxy-3-methyl-1-hexenyl N,N-diisopropylcarbamate 
• 121408-94-4 (R)-(+)-isobutyl O-benzyllactate 
• 100-39-0 benzyl bromide 
• 53346-05-7 (R)-2-benzyloxypropanal 
• 121408-80-8 (1R,2S,3R,4R,5R)-5-Benzyloxy-1,2-epoxy-4-hydroxy-3-methylhexyl N,N-diisopropylcarbamate 
• 110418-30-9 (1Z,3R,4R,5S)-5-Benzyloxy-4-hydroxy-3-methyl-1-hexenyl N,N-diisopropylcarbamate 
• 81445-44-5 (S)-2-(benzyloxy)propanal 
• 54783-72-1 ethyl (S)-2-(benzyloxy)propionate 
• 110418-31-0 (1R,2S,3R,4R,5S)-5-Benzyloxy-1,2-epoxy-4-hydroxy-3-methylhexyl N,N-diisopropylcarbamate 
• 118759-56-1 (1Z,3S,4S,5R)-5-Benzyloxy-4-hydroxy-3-methyl-1-hexenyl N,N-diisopropylcarbamate 
• 121408-81-9 (1S,2R,3S,4S,5R)-5-Benzyloxy-1,2-epoxy-4-hydroxy-3-methylhexyl N,N-diisopropylcarbamate 
• 121408-72-8 Trifluoro-methanesulfonic acid (2R,3S,4S,5R)-5-((S)-1-benzyloxy-ethyl)-2-methoxy-4-methyl-tetrahydro-furan-3-yl ester 
• 121408-75-1 Methanesulfonic acid (2R,3S,4S,5R)-5-((S)-1-benzyloxy-ethyl)-2-methoxy-4-methyl-tetrahydro-furan-3-yl ester 
• 121408-73-9 Methyl 2-O-acetyl-5-O-benzyl-3,6-dideoxy-3-C-methyl-α-L-altrofuranoside 

Downstream Products

• 84247-24-5 1-O-benzyl-2,4,7-trideoxy-2,4-di-C-methyl-D-glycero-L-ido-heptitol 
• 79386-76-8 2-O-benzyl-1,4,7-trideoxy-5,6-O-isopropylidene-4-C-methyl-D-glycero-L-gulo-heptitol 
• 84247-22-3 (2S,3R,4S)-1-Benzyloxy-2-methyl-4-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-pentan-3-ol 
• 79386-79-1 3-O-acetyl-2-O-benzyl-1,4,7-trideoxy-5,6-O-isopropylidene-4-C-methyl-D-glycero-L-gulo-heptitol 
• 79391-45-0 (2R,3R,4S,5R,6R)-5-Benzyloxy-2-((2R,3R,4S,6R)-4,6-dimethoxy-3-methyl-tetrahydro-pyran-2-yl)-4-methyl-6-((4S,5S)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-heptane-1,3-diol 
• 79391-45-0 (2R,3S,4S,5R,6R)-5-Benzyloxy-2-((2R,3R,4S,6R)-4,6-dimethoxy-3-methyl-tetrahydro-pyran-2-yl)-4-methyl-6-((4S,5S)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-heptane-1,3-diol 
• 79391-45-0 (2S,3S,4S,5R,6R)-5-Benzyloxy-2-((2R,3R,4S,6R)-4,6-dimethoxy-3-methyl-tetrahydro-pyran-2-yl)-4-methyl-6-((4S,5S)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-heptane-1,3-diol 
• 79391-44-9 (2R,3R,4S,5R,6R)-5-Benzyloxy-2-((2S,3R,4S,6R)-4,6-dimethoxy-3-methyl-tetrahydro-pyran-2-yl)-4-methyl-6-((4S,5S)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-heptan-3-ol 
• 79391-44-9 (2S,3R,4S,5R,6R)-5-Benzyloxy-2-((2S,3R,4S,6R)-4,6-dimethoxy-3-methyl-tetrahydro-pyran-2-yl)-4-methyl-6-((4S,5S)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-heptan-3-ol 
• 79391-44-9 (2R,3S,4S,5R,6R)-5-Benzyloxy-2-((2S,3R,4S,6R)-4,6-dimethoxy-3-methyl-tetrahydro-pyran-2-yl)-4-methyl-6-((4S,5S)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-heptan-3-ol 
• 79391-44-9 (2S,3S,4S,5R,6R)-5-Benzyloxy-2-((2S,3R,4S,6R)-4,6-dimethoxy-3-methyl-tetrahydro-pyran-2-yl)-4-methyl-6-((4S,5S)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-heptan-3-ol 
• 79391-41-6 (4S,5R,6R)-5-Benzyloxy-2-((2R,3R,4S,6R)-4,6-dimethoxy-3-methyl-tetrahydro-pyran-2-yl)-4-methyl-6-((4S,5S)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-hept-1-en-3-ol 
• 79386-87-1 (2R,3R,4S,6R)-2-[(Z)-(3S,4R,5R)-4-Benzyloxy-1,3-dimethyl-5-((4S,5S)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-hex-1-enyl]-4,6-dimethoxy-3-methyl-tetrahydro-pyran 
• 79386-83-7 3-O-benzyl-2,4,7-trideoxy-5,6-O-isopropylidene-2,4-di-C-methyl-L-glycero-D-galacto-heptose trimethylene dithioacetal 

Relevant academic research and scientific papers

Enantiomerically Pure 2-(Carbamoyloxy)oxiranes and Their Utility in the Synthesis od D- and L-3,6-Dideoxy-3-C-methylhexofuranosides via the Homoaldol Reaction

As an example of a novel flexible strategy in the rapid enantioselective construction of branched carbohydrate analogues by the homoaldol reaction, the title compounds were synthesized. α-Metalated (E)-2-butenyl N,N-diisopropylcarbamate is added to (S)- or (R)-2-benzyloxypropanal.The homoaldol adducts are epoxidized; methanolysis affords furanosides of branched 3,6-dideoxyaldohexoses, or, hydrolysis yields the furanoses.

A CHIRAL SYNTHESIS OF 3,5,7-TRI-O-BENZYL-1,4,6-TRIDEOXY-4,6-DI-C-METHYL-keto-L-ido-2-HEPTULOSE, A SYNTHETIC SEGMENT OF THE C-1 - C-6 PORTION OF ERYTHRONOLIDE A

3,6-Dideoxy-1,2-O-isopropylidene-3-C-methyl-α-D-glucofuranose (9) was prepared from methyl 4,6-O-benzylidene-3-deoxy-3-C-methyl-α-D-glucopyranoside via 3-deoxy-1,2-O-isopropylidene-3-C-methyl-α-D-glucofuranose (5) in 61percent yield.The key intermediates,