121410-95-5

Basic information

• Product Name: O-cyclododecyl O-phenyl thionocarbonate
• Synonyms: O-cyclododecyl O-phenyl thionocarbonate
• CAS NO: 121410-95-5
• Molecular Weight: 320.496
• Mol File: 121410-95-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: O-cyclododecyl O-phenyl thionocarbonate(CAS DataBase Reference)
• NIST Chemistry Reference: O-cyclododecyl O-phenyl thionocarbonate(121410-95-5)
• EPA Substance Registry System: O-cyclododecyl O-phenyl thionocarbonate(121410-95-5)

Safety Data

• Hazardous Substances Data: 121410-95-5(Hazardous Substances Data)

Upstream product

• 108-95-2 phenol 
• 1724-39-6 cyclododecanol 
• 1005-56-7 phenylcarbonochloridothioate 

Downstream Products

• 294-62-2 cyclododecane 

Relevant articles and documents

Evaluation of cyclopentyl methyl ether (CPME) as a solvent for radical reactions

We have explored the potential of cyclopentyl methyl ether (CPME) as a solvent for radical reactions. Hydrostannation, hydrosilylation, hydrothiolation, and tributyltin hydride mediated reductions were successfully carried out in CPME. GC-MS analysis indicated that CPME degraded into methyl pentanoate, cyclopentanone, 2-cyclopenten-1-ol, and cyclopentanol under thermal radical conditions, albeit only slightly. We also achieved radical-containing one-pot reactions in CPME as a demonstration of its applicability to multi-step reactions.

The invention of radical reactions. Part XXXI. Diphenylsilane: A reagent for deoxygenation of alcohols via their thiocarbonyl derivatives, deamination via isonitriles, and dehalogenation of bromo- and iodo- compounds by radical chain chemistry

Various thionocarbonates and xanthates of alcohols and bis-xanthates of vic-diols are readily deoxygenated to the corresponding hydrocarbons or olefins, while bromides and iodides are dehalogenated with diphenylphenylsilane in good yield.

Facile Reduction of Dithiocarbonates Derived from Secondary Alcohols with n-Bu3SnH-Et3B and Synthesis of 2-Furanthiones and 2-Furanones by Intramolecular Addition of Alkoxythiocarbonyl Free Radicals to Acetylenic Linkages

The reduction of dithiocarbonates or thiocarbonates by n-Bu3SnH-Et3B easily gives the corresponding hydrocarbons.The intermediate alkoxythiocarbonyl radical equivalents are trapped by properly located carbon-carbon multiple bonds.The dithiocarbonates derived from either homopropargylic or homoallylic alcohols produce tetrahydrofuranones upon treatment with n-Bu3SnH-Et3B.Application of this new method to the conversion of carbonyl compounds into olefins is also described.