121422-99-9

Upstream product

• 109907-16-6 {C₆H₂(C(CH₃)3)3}PCHCHP{C₆H₂(C(CH₃)3)3} 
• 53248-43-4 pentacarbonyl(tetrahydrofuran)molybdenum⁽⁰⁾ 
• 121422-99-9 (E/E)-decacarbonyl(η1,η1-1,4-bis{2,4,6-tri(t-butyl)phenyl}-1,4-diphospha-(1,3)butadiene)dimolybdenum 

Downstream Products

• 121422-99-9 (E/Z)-decacarbonyl(η1,η1-1,4-bis{2,4,6-tri(t-butyl)phenyl}-1,4-diphospha-(1,3)butadiene)dimolybdenum 

Relevant academic research and scientific papers

Niederkoordinierte Phosphoverbindungen LXVIII. Zur Komplexierung phosphorsubstituierter Butadiensysteme

Treatment of the 1,3-diphospha(1,3)butadiene (I) with Ni(CO)4 or Fe2(CO)9 affords η1- or η4-coordination to a M(CO)3 fragment.Complex formation by the reaction of 1,4-diphospha(1,3)butadiene (IV) with C7H8M(CO)4 or M(CO)5THF (M = Cr, Mo, W) yields the doubly η1-coordinated compounds, which readily undergo E/Z-isomerization compared to IV.Bonding of a Mo(CO)4 fragment to the 1,2,4-triphospha(1,3)butadiene (VIII) was attained by two different reactions.