1214346-49-2Relevant academic research and scientific papers
Pd-containing organopolyoxometalates derived from Dawson polyoxometalate [P2W15V3O62]9-: Lewis acidity and dual site catalysis
Riflade, Benoit,Lachkar, David,Oble, Julie,Li, Joaquim,Thorimbert, Serge,Hasenknopf, Bernold,Lacote, Emmanuel
, p. 3860 - 3863 (2014)
Grafting of a palladium complex to the Dawson vanadotungstate polyanion [P2W15V3O62]9- via an organic ligand generates a large family of pincer-type hybrid polyoxometalates. The palladium-POM derivatives have dual catalytic properties. Unlike their parent inorganic polyanions, they catalyze allylations while retaining their oxidant character, which leads to single-pot dual site catalysis. This opens a new route for multicatalytic reactions.
