1214913-12-8

Basic information

• Product Name: [1-(4-bromophenyl)allyl]dimethylphenylsilane
• Synonyms: [1-(4-bromophenyl)allyl]dimethylphenylsilane
• CAS NO: 1214913-12-8
• Molecular Weight: 331.327
• Mol File: 1214913-12-8.mol

Chemical Properties

• CAS DataBase Reference: [1-(4-bromophenyl)allyl]dimethylphenylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: [1-(4-bromophenyl)allyl]dimethylphenylsilane(1214913-12-8)
• EPA Substance Registry System: [1-(4-bromophenyl)allyl]dimethylphenylsilane(1214913-12-8)

Safety Data

• Hazardous Substances Data: 1214913-12-8(Hazardous Substances Data)

Upstream product

• 104293-07-4 (E)-1-bromo-4-(3-chloroprop-1-en-1-yl)benzene 
• 185990-03-8 dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane 
• 768-33-2 phenyldimethylsilyl chloride 
• 96090-12-9 1-(4-bromophenyl)-1-propen-3-yl bromide 

Relevant articles and documents

Copper-catalyzed Si-B bond activation in branched-selective allylic substitution of linear allylic chlorides

The harder they come, the better they leave! Chloride is superior to all common leaving groups in the γ-selective allylic substitution of linear precursors. This approach involves a novel copper-catalyzed Si-B bond activation (see scheme; γ/α≥98:2, 7-examples; Si=SiMe2Ph and B=Bpin with pin=pinacolato).

Expedient access to branched allylic silanes by copper-catalysed allylic substitution of linear allylic halides

An unprecedented copper-catalysed allylic transposition enables the regioselective synthesis of branched allylic silanes from linear allylic halides through direct C-Si bond formation.