1215086-63-7Relevant academic research and scientific papers
Intramolecular reductive ketone-alkynoate coupling reaction promoted by (η2-propene)titanium
Schaefer, Christian,Miesch, Michel,Miesch, Laurence
, p. 3253 - 3257 (2012/06/01)
Intramolecular reductive coupling of cycloalkanones tethered to alkynoates in the presence of (η2-propene)titanium was successfully performed to provide hydroxy-esters in a diastereoselective manner. Subsequent lactonization afforded angularly
Synthesis of racemic and enantiomerically pure acetylenic -keto esters derived from 2-methyl-1,3-cycloalkanediones and 2-methylcycloalkanones respectively
Geoffroy, Philippe,Ballet, Marie-Paule,Finck, Sidonie,Marchioni, Eric,Marcic, Christophe,Miesch, Michel
experimental part, p. 171 - 179 (2010/04/28)
Racemic and enantiomerically pure alkynyl esters tethered, respectively, to 2-methyl-1,3-cycloalkanediones and 2-methylcycloalkanones were readily obtained starting from common intermediates, which were available on large scale.
