1215096-67-5Relevant academic research and scientific papers
Efficient preparation of 1,3-Diol derivatives with three contiguous stereocenters by an enantioselective direct aldol-tishchenko reaction
Ichibakase, Tomonori,Nakajima, Makoto
, p. 3145 - 3151 (2012/11/13)
1,3-Diol derivatives with three contiguous stereocenters were efficiently prepared by an enantioselective direct aldol-Tishchenko reaction catalyzed by dilithium 3,3-diphenylbinaphtholate. The reactions of acyclic ketones as aldol donors gave 1,2-syn-1,3-
Direct enantioselective aldol-tishchenko reaction catalyzed by chiral lithium diphenylbinaphtholate
Ichibakase, Tomonori,Nakajima, Makoto
supporting information; experimental part, p. 1579 - 1581 (2011/05/03)
Chiral lithium diphenylbinaphtholate is an effective catalyst for the enantioselective aldol-Tishchenko reaction, affording 1,3-diol derivatives with three contiguous chiral centers and high stereoselectivities. Successive aldol-aldol-Tishchenko reactions
Baker's yeast reduction of β-hydroxy ketones
Acetti, Daniela,Brenna, Elisabetta,Fuganti, Claudio,Gatti, Francesco G.,Serra, Stefano
experimental part, p. 142 - 151 (2010/03/24)
Reduction of β-hydroxy ketones to the corresponding 1,3-diols by baker's yeast was investigated, in order to develop methods for simultaneous control over the configurations of multiple stereogenic centres. The reactions were found to be enantiospecific a
