1215119-96-2Relevant academic research and scientific papers
Palladium-Catalyzed Alkynylation of Enones with Alkynylsilanes via C-C Bond Activation
Dai, Hui-Xiong,Li, Ling-Jun,Liu, Yu-Wen,Xu, Hui
, (2022/05/20)
We report herein the synthesis of 1,3-enynes via palladium-catalyzed cross-coupling between enone derivatives and alkynylsilanes. The employment of an appropriate pyridine-oxazoline ligand is the key to the C-C cleavage and the high E/Z stereoselectivity.
Suzuki coupling reactions of (E)- and (Z)-chloroenynes with boronic acids: Versatile access to functionalized 1,3-enynes
Tikad, Abdellatif,Hamze, Abdallah,Provot, Olivier,Brion, Jean-Daniel,Alami, Mouad
experimental part, p. 725 - 731 (2010/03/24)
A stereoselective, palladium-catalyzed, cross-coupling reaction between chloroenynes 4 and boronic acids was successfully developed. This procedure is general and provides de-sired functionalized enynes 1 in high yields. The scope and limitations of this new reaction are described.
