12152-94-2

Basic information

• Product Name: FERROCENEBORONIC ACID
• Synonyms: FERROCENEBORONIC ACID;Ferroceneboronic acid (contains varying amounts of anhydride);ferrocenemetaboric acid;cyclicboronatingreagentforGC/MS;FERROCENEBORONICACID(CONTAINSVARYINGAMOUNTSOFANHYDRIDE)[CYCLICBORONATINGREAGENTFORGC/MS];(Boronocyclopentadienyl)cyclopentadienyl iron;NSC 119337;Ferroceneboronic Acid [Cyclic boronating reagent for GC/MS]
• CAS NO: 12152-94-2
• Molecular Formula: C₁₀H₁₂B₂FeO₄
• Molecular Weight: 229.85
• EINECS: 235-272-1
• Product Categories: Electrochemical Detection (HPLC Labeling Reagents);Analytical Chemistry;B (Classes of Boron Compounds);Boronic Acid, etc. (GC Derivatizing Reagents);Boronic Acids;Classes of Metal Compounds;Fe (Iron) Compounds;Ferrocenes;GC Derivatizing Reagents;HPLC Labeling Reagents;Metallocenes;Transition Metal Compounds;Aryl;Boronic Acids;Boronic Acids and Derivatives
• Mol File: 12152-94-2.mol
• Article Data: 2

Chemical Properties

• Melting Point: 145-150 °C (dec.)(lit.)
• Boiling Point: 267.1 °C at 760 mmHg
• Flash Point: 115.3 °C
• Appearance: /
• Vapor Pressure: 0.00113mmHg at 25°C
• Solubility: slightly sol. in Ether
• CAS DataBase Reference: FERROCENEBORONIC ACID(CAS DataBase Reference)
• NIST Chemistry Reference: FERROCENEBORONIC ACID(12152-94-2)
• EPA Substance Registry System: FERROCENEBORONIC ACID(12152-94-2)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37
• WGK Germany: 3
• Hazardous Substances Data: 12152-94-2(Hazardous Substances Data)

Usage

Uses

Redox-acitce electrochemical probe to monitor interactions involving sugarsReactant involved in:Synthesis of ferrocene-appended subporphyrins for electrochemical property studiesSynthesis of catalysts for polymerization of olefinsSuzuki-coupling reaction with organic triflatesCatalytic ortho-lithiation

InChI:InChI=1/C5H6BO2.C5H5.Fe/c7-6(8)5-3-1-2-4-5;1-2-4-5-3-1;/h1-4,7-8H;1-5H;/q2*-1;+2

Upstream product

• 102-54-5 ferrocene 
• 688-74-4 boric acid tributyl ester 

Downstream Products

• 640298-72-2 [Fe(η5-C5H4-4-(C6H3(CH2NMe2)2-2,6))2] 
• 532938-95-7 [Fe(η5-C5H4-C6H4-4-C5H4N)2] 
• 402718-81-4 (S)-1,1'-(1,1'-binaphthyl-2,2'-diyl)ferrocene 
• 604-53-5 1,1'-bisnaphthalene 
• 102-54-5 ferrocene 

Related news

Voltammetric response of FERROCENEBORONIC ACID (cas 12152-94-2) to diol and phenolic compounds as possible pollutants08/01/2019

A voltammetric determination of possible organic pollutants such as diol and phenolic compounds in water was studied using ferroceneboronic acid (FBA) as a redox-active marker. A cyclic voltammogram of FBA exhibited a pair of oxidation and reduction peaks at 230 and 170 mV at pH 7.0, respectivel...detailed

FERROCENEBORONIC ACID (cas 12152-94-2) for the electrochemical probing of interactions involving sugars07/31/2019

Ferroceneboronic acid (FcBA) was used as a redox-active probe suitable for monitoring of diol–boronate interactions. Voltammetric and amperometric measurements allowed to detect FcBA forms – free and bound in the boronate complex. In this way, the complexation interaction was studied for a set...detailed

Interaction of FERROCENEBORONIC ACID (cas 12152-94-2) with diols at aqueous and non-aqueous conditions - signalling and binding abilities of an electrochemical probe for saccharides07/30/2019

Ferroceneboronic acid (FcBA) was employed as a model compound for clarification of binding and signalling properties of molecular probe for saccharides. As the simplest electrochemically active boronic acid, its interactions with diverse diols were studied in homogeneous phase under aqueous and ...detailed

Relevant articles and documents

Palladium-catalyzed arylation of ferrocene derivatives: a convenient high yield route to 1,1'-bis(halophenyl)ferrocenes

The Pd-catalyzed cross-coupling reaction between halobenzenes and ferrocene-1,1'-diboronic acid is reported.Condensation proceeds smoothly to give 1,1'-diphenyl- and 1,1'-bis(halophenyl)-substituted ferrocenes bearing fluoro, chloro and bromo substituents in good yields.An effective synthesis of the intermediate ferrocene-1,1'-diboronic acid is described.