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High quality ferrocene supplier in China
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No Data 1 Kilogram 30 Metric Ton/Month Simagchem Corporation Contact Supplier
Factory Supply Ferrocene
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No Data 1 Kilogram 400 Metric Ton/Day Ality Chemical Corporation Contact Supplier
Ferrocene
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No Data 1 Kilogram 1000 Metric Ton/Year Xunteng International Trading Co.,Limited Contact Supplier
Supply high quality Ferrocene
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No Data 25 Kilogram 5000 Metric Ton/Year Aecochem Corp. Contact Supplier
Ferrocene suppliers in China
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USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
High purity Ferrocene with high quality and best price cas:102-54-5
Cas No: 102-54-5
USD $ 10.0-15.0 / Kilogram 1 Kilogram 99999 Kilogram/Year Hangzhou Dingyan Chem Co., Ltd Contact Supplier
ferrocene
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USD $ 500.0-500.0 / Gram 1000 Gram 10 Metric Ton/Month Hebei yanxi chemical co.,LTD. Contact Supplier
ferrocene 99% 102-54-5
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No Data 1 Metric Ton 500 Metric Ton/Year Hefei TNJ chemical industry co.,ltd Contact Supplier
Ferrocene
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No Data 1 Kilogram 20 Metric Ton/Day Henan Allgreen Chemical Co.,Ltd Contact Supplier
102-54-5 Ferrocene
Cas No: 102-54-5
USD $ 40.0-50.0 / Gram 1 Gram 1000 Metric Ton/Day WUHAN MULEI NEW MATERIAL CO., LTD Contact Supplier

102-54-5 Usage

Chemical Properties

It is an orange needles like crystal with its melting point being 172.5-173 ℃. It undergoes sublimation at temperature higher than 100 ℃. Its boiling point is 249 ℃. It is soluble in dilute nitric acid, concentrated sulfuric acid, benzene, ether, petroleum ether and tetrahydrofuran. It can generate bluish fluorescence-containing deep red solution in dilute nitric acid and concentrated sulfuric acid. It is insoluble in water, 10% sodium hydroxide and hot concentrated hydrochloric acid. In the boiling solution of these solvents, ferrocene is neither dissolved nor decomposed. It can be evaporated together with water vapor. It has a smell similar to camphor and is stable in air. It has a strong property of UV absorbing and has great thermostability which can withstand the heating at a temperature as high as 470 ℃.

Flammability and hazard characteristics

flammable with the combustion generating iron-containing acrid smoke

Extinguishing agent

Water, carbon dioxide, dry, sandy soil.

Acute toxicity

Oral-rat LD50: 1320 mg/kg; Oral-Mouse LD50: 832 mg/kg.

Professional standards

TWA 10 mg/m3; STEL 20 mg/m3

Category

toxic substances

Uses

Ferrocene can be used as the additives of rocket fuel, the antiknock agent of gasoline and the curing agent of rubber and silicone resin as well as the ultraviolet absorber. The Vinyl derivative of ferrocene can be subject to ethylenic polymerization to obtain the metal-containing polymers of carbon chain skeleton which can be used as the outer coating of spacecraft. It has been found early regarding the smoke abatement effect and combustion effect of ferrocene. No matter whether being supplied in solid fuel, liquid fuel or gas fuel, it can always exert this kind of effect and this effect is more significant especially for hydrocarbons with smoke upon burning. Supplement it into the gasoline has a very good anti-hunt effect. However, due to the deposition of the iron oxide in park plug which can negatively affect ignition, its application is limited, therefore, some people also apply de-iron mixture in order to reduce the deposition phenomenon of iron. Supplement of ferrocene to the kerosene or diesel oil, due to the absence of ignition device in the engine, will have fewer adverse effects on it. In addition to the smoke abatement and combustion facilitating effect in the combustion, it also has effect of promoting the conversion of carbon monoxide into carbon dioxide. In addition, it can improve the heat of combustion and increase power efficiency to achieve the effects of energy saving and air pollution reduction. Supplement of ferrocene to the boiler fuel oil can reduce tobacco production and nozzle deposition. Supplement of 0.1% ferrocene in diesel can remove smoke by 30-70%, save fuel by 10-14%, and increase the power by 10%. There are even many more reports regarding the application of ferrocene in solid fuel of rocket fuel. Moreover, there are even cases regarding supplying it in pulverized coal for smoke-reduction agent. Upon applying the polymer water as fuel, supplement of ferrocene can reduce the smoke by several times. It can also be used as the smoke-reducing additive. In addition to the above applications, ferrocene also has other applications. When used as iron fertilizer, it can facilitate the absorption of plants on iron and increase the iron content of crops. Moreover, its derivatives can be used as pesticides. Ferrocene also has a lot of applications in industry and organic synthesis. For example, its derivatives can be used as the antioxidant of rubber or polyethylene, the stabilizer of polyurea ester, the catalyst of isobutene spasm methylation, the decomposition catalyst of polymer peroxide, and for increasing the yield of para-chlorotoluene produced during the process of chlorination of toluene. In other areas, it can also be used as anti-load additive of lubricants as well as the promoting agent of abrasive materials.
It can be used as catalyst and the antiknock additive of gasoline as well as energy-saving additives for combustion promotion and smoke removal; it can be applied to various kinds of fuels such as diesel, gasoline, heavy oil and coal. Supplement of 0.1% ferrocene into diesel can save fuel by 10-14%, increase the efficiency by 10-13%, and reduce the degree of smoke in exhaust by 30-80 ‰. In addition, addition of 0.3 ‰ to the heavy oil and addition of 0.2% ferrocene to coal can both decrease the fuel consumption rate while the degree of smoke is also reduced by 30%.
Ferrocene is a kind of sandwich-containing metal compound. Ferrocene and its derivatives, because of their own characteristics such as hydrophobicity, bio-oxidability, aroma, stability, low resistance, biological activity, has a wide range of application such as catalyst, the antiknock additive of gasoline, high-temperature lubricant, the intermediates of high-temperature polymer and UV absorber.

Reactivity Profile

Ferrocene reacts violently with tetranitromethane. . Contact of tetranitromethane with Ferrocene under various conditions leads to violent explosion, [Trans. Met. Chem., 1979, 4, 207-208].

A kind of organic transition metal compound with aromatic proper

Ferrocene is a kind of organic transition metal compound with aromatic nature. It is also called as dicyclopentadienyl iron. It contains a divalent iron cation and two cyclopentadienyl anions in its molecular structure. It is also the raw materials for production of ferrocenecarboxylic acid. In 1950s of the last century, people had first successfully produced it with the reaction between cyclopentadienyl magnesium bromide and anhydrous ferric chloride. At room temperature, it is orange needle crystal powder with a similar smell as camphor and belongs to non-polar compound. It is soluble in many organic solvents such as methanol, ethanol, ethyl ether, petroleum ether, gasoline, kerosene, diesel oil, methylene chloride, benzene, toluene, and xylene, Because of the large polarity of ethanol polarity, it is usually recommended to dissolve it with toluene. It is insoluble in water but soluble in concentrated sulfuric acid. It is also insoluble and doesn’t decompose in boiling caustic soda solution and hydrochloric acid. It molecule exhibits polarity with higher thermal stability, chemical stability and radiation resistance. It has wide range of application in industry, agriculture, medicine, aerospace, energy, environmental protection and other industries. Main applications are described below:
(1)It can be used as the fuel saving smoke suppressants and anti-knock agent. For example, it can be used for the production of gasoline antiknock agent, the fuel catalyst of rocket propellant and also the solid fuels of aerospace.
(2) It can be used as the catalyst such as catalyst for the production of ammonia, as the curing agent of silicone rubber; it can prevent the degradation of polyethylene by light; when applied to agricultural mulch, it can break its natural degradation without affecting the cultivation and fertilization within a certain time.
(3) It can be used as a gasoline anti-knock agent. It can substitute gasoline toxic tetraethyl lead for being used as the anti-knock agent and for production of high-grade unleaded petrol in order to eliminate the contamination of the environment and poisoning to human body by discharge of fuel.
(4) It can be used as radiation absorbers, heat stabilizers, light stabilizers, and smoke-retardants.
(5) For the chemical properties, ferrocene is similar to aromatic compounds which is not prone to have addition reaction but prone to have electrophilic substitution reaction. It can also participate in metallization, acylation, alkylation, sulfonation, formylation and ligand exchange reaction, which can be used for production of derivative with a wide range of applications.
The above information is edited by the Chemicalbook of Dai Xiongfeng.

Storage properties

warehouse: ventilated, low temperature and dry; Store it separately from oxidants.

Fire Hazard

Flash point data for Ferrocene are not available. Ferrocene is probably combustible.

Production method

It can be produced either by the heating reaction between iron powder and cyclopentadiene in nitrogen atmosphere of 300 ℃ or the reaction between anhydrous ferric chloride together with the sodium cyclopentadienyl in tetrahydrofuran. Alternatively, it can also produced by electrolytic synthesis method. Taking cyclopentadiene, ferrous chloride, and diethylamine as raw material for synthesis of ferrocene can operate according to the following protocol. Upon stirring, add anhydrous ferric chloride (FeCl3) in several times to the tetrahydrofuran solution; further add iron powder into it and have heating reflux for 4.5 h under the protection of nitrogen gas, resulting in ferrous chloride solution. Further remove tetrahydrofuran solvent by evaporation under reduced pressure to give nearly dry residue. Under ice-cooling condition, add the mixture of cyclopentadienyl and diethylamine and stir vigorously at room temperature for 6-8h; remove the excess amount of amine through evaporation under reduced pressure and extract the residue with petroleum ether under reflux. The extract is subject to immediate filtering; evaporate the solvent to obtain ferrocene crude product. Employ pentane or cyclohexane for recrystallization, or apply sublimation method for extract purified product with the yield of refined product being 73-84%.

Uses

Antiknock additive for gasoline; catalyst.

Purification Methods

Purify it by crystallisation from pentane or cyclohexane (also *C6H6 or MeOH can be used). It is moderately soluble in Et2O and sublimes readily above 100o. Crystallisation from EtOH gave material m 172.5-173o. [Wilkinson Org Synth Coll Vol IV 473 1963, Miller J Chem Soc 632 1952.] It has also been crystallised from methanol and sublimed in vacuo. [Saltiel et al. J Am Chem Soc 109 1209 1987, Beilstein 16 IV 1783.]

Chemical Properties

solid

General Description

Orange crystalline solid or orange-yellow powder. Sublimes above 212°F. Camphor odor.

Air & Water Reactions

Sensitive to prolonged exposure to air and may be sensitive to light. Insoluble in water.

Toxicity grading

poisoning
InChI:InChI=1/2C5H5.Fe/c2*1-2-4-5-3-1;/h2*1-3H,4H2;/rC10H10Fe/c1-2-6-9(5-1)11-10-7-3-4-8-10/h1-5,7H,6,8H2

102-54-5 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Aldrich (F408)  Ferrocene  98% 102-54-5 F408-500G 1,272.96CNY Detail
Aldrich (F408)  Ferrocene  98% 102-54-5 F408-100G 397.80CNY Detail
Aldrich (F408)  Ferrocene  98% 102-54-5 F408-5G 279.63CNY Detail
Alfa Aesar (B25007)  Ferrocene, high purity, 99.5%    102-54-5 1000g 2171.0CNY Detail
Alfa Aesar (B25007)  Ferrocene, high purity, 99.5%    102-54-5 250g 969.0CNY Detail
Alfa Aesar (B25007)  Ferrocene, high purity, 99.5%    102-54-5 50g 338.0CNY Detail
Alfa Aesar (87202)  Ferrocene, 99%    102-54-5 1kg 1468.0CNY Detail
Alfa Aesar (87202)  Ferrocene, 99%    102-54-5 250g 801.0CNY Detail
Alfa Aesar (87202)  Ferrocene, 99%    102-54-5 50g 297.0CNY Detail

102-54-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name ferrocene

1.2 Other means of identification

Product number -
Other names Di(cyclopentadienyl)iron

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:102-54-5 SDS

102-54-5Synthetic route

ferrocenyl(triphenylphosphine)gold

ferrocenyl(triphenylphosphine)gold

ferrocene
102-54-5

ferrocene

Conditions
ConditionsYield
With potassium cyanide In chloroform; water byproducts: P(C6H5)3; (Ar); shaking a soln. of the Au complex in CHCl3 with aq. KCN, 8 h; sepn. of the org. layer, drying over K2CO3, evapn. to dryness; products determined by thin-layer chromy. and 1H-NMR;100%
In not given with electrophilic reacgents;;
ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

dicarbonyl(η5-cyclopentadienyl)(η1-7-methoxy-1-cycloheptenyl)iron
95865-41-1

dicarbonyl(η5-cyclopentadienyl)(η1-7-methoxy-1-cycloheptenyl)iron

A

ferrocene
102-54-5

ferrocene

B

dicarbonyl(η5-cyclopentadienyl)(η1-7-methoxycycloheptene-1-carbonyl)iron
95865-47-7

dicarbonyl(η5-cyclopentadienyl)(η1-7-methoxycycloheptene-1-carbonyl)iron

Conditions
ConditionsYield
With `CO In dichloromethane Addn. of Cp2FeBF4 to iron-compd. (methylene chloride, 55 psiCO, 1h).; Removal of solvent (vacuo), elution with hexane (alumina column) gives yellow band of ferrocene, elution with CH2Cl2 gives yellow band of dicarbonyl complex, elem. anal.;A n/a
B 99%
ferrocenium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate
156301-37-0

ferrocenium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

([3,5-(2,4,6-i-Pr3C6H2)2C6H3NCH2CH2]3N)Mo(η2-C2H2)

([3,5-(2,4,6-i-Pr3C6H2)2C6H3NCH2CH2]3N)Mo(η2-C2H2)

A

ferrocene
102-54-5

ferrocene

[([3,5-(2,4,6-i-Pr3C6H2)2C6H3NCH2CH2]3N)Mo(C2H2)][B(3,5-(CF3)2C6H3)4]

[([3,5-(2,4,6-i-Pr3C6H2)2C6H3NCH2CH2]3N)Mo(C2H2)][B(3,5-(CF3)2C6H3)4]

Conditions
ConditionsYield
In benzene under N2 atm. to soln. Mo complex in benzene (Cp2Fe)(BAr'4) was added and stirred for 30 min; volatiles were removed in vacuo, residue was dissolved in heptane, ppt. was dried in high vac.; elem. anal.;A n/a
B 99%
ferrocenium trifluoromethanesulfonate

ferrocenium trifluoromethanesulfonate

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

A

ferrocene
102-54-5

ferrocene

B

tri(o-tolyl)phosphonium trifluoromethanesulfonate salt

tri(o-tolyl)phosphonium trifluoromethanesulfonate salt

Conditions
ConditionsYield
With C26H46ClO3Ru2S2(1+)*CF3O3S(1-); hydrogen In dichloromethane at 20℃; under 760.051 Torr; for 11h; Catalytic behavior; Inert atmosphere;A 99%
B 98%
cyclopenta-1,3-diene
542-92-7

cyclopenta-1,3-diene

iron(II) bromide

iron(II) bromide

ferrocene
102-54-5

ferrocene

Conditions
ConditionsYield
With iron; diethylamine In further solvent(s) further solvents: mixt. of HN(C2H5)2, CH3OH, DME and (C6H5CH2N(CH3)3)OH; amine method; FeBr2 and Fe from Fe and Br2, Fe excess;;98%
With diethylamine In 1,2-dimethoxyethane; diethylamine amine method; FeBr2 from Fe and Br2;;85%
With diethylamine In 1,2-dimethoxyethane; diethylamine amine method; FeBr2 from Fe and Br2;;85%
With diethylamine In diethylamine byproducts: HBr;4%
ferrocenium hexafluorophosphate

ferrocenium hexafluorophosphate

tetra-n-butylammonium tetramethylaurate(III)

tetra-n-butylammonium tetramethylaurate(III)

A

ferrocene
102-54-5

ferrocene

Conditions
ConditionsYield
In acetonitrile byproducts: CH4, C2H6; inert atmosphere;A 92%
B 98%
In tetrahydrofuran byproducts: CH4, C2H6; inert atmosphere;A 94%
B 95%
ferrocenium hexafluorophosphate

ferrocenium hexafluorophosphate

tetra-n-butylammonium tetramethylaurate(III)

tetra-n-butylammonium tetramethylaurate(III)

triphenylphosphine
603-35-0

triphenylphosphine

A

ferrocene
102-54-5

ferrocene

trimethyl(triphenylphosphine)gold(III)

trimethyl(triphenylphosphine)gold(III)

Conditions
ConditionsYield
In tetrahydrofuran byproducts: CH4; He-atmosphere; -196°C, addn. of Cp2FePF6 to soln. of aurate and PPh3; not sepd., NMR-spectroscopy;A 98%
B 98%
In diethyl ether byproducts: CH4, C2H6; inert atmosphere;A 95%
B 94%
In acetonitrile byproducts: CH4; inert atmosphere; -40°C;A 94%
B 89%
1,2-bis((η6-4-chlorophenoxy-η5-cyclopentadienyl)iron)benzene hexafluorophosphate

1,2-bis((η6-4-chlorophenoxy-η5-cyclopentadienyl)iron)benzene hexafluorophosphate

A

ferrocene
102-54-5

ferrocene

B

1,2-bis-(4-chlorophenoxy)benzene
153288-01-8

1,2-bis-(4-chlorophenoxy)benzene

Conditions
ConditionsYield
In dichloromethane; acetonitrile Irradiation (UV/VIS); addn. of diiron-complex dissolved in CH2Cl2/CH3CN to a photolysis tube, purging with N2 for 30 min, irradiation under intense visible light (Xenon lamp) for 4 h; concn. by evapn. under reduced pressure, column chromy., elution (hexane) gives yellow band of ferrocene, elution (hexane/CHCl3) gives benzene-compd., evapn. to dryness, elem. anal.;A n/a
B 98%
[C6H5S(O)CH2](1-)*Li(1+)=[C6H5S(O)CH2]Li
59501-96-1

[C6H5S(O)CH2](1-)*Li(1+)=[C6H5S(O)CH2]Li

(C5H5)Fe[P(OC6H5)3]2Cl
84430-52-4

(C5H5)Fe[P(OC6H5)3]2Cl

A

ferrocene
102-54-5

ferrocene

B

bis(phenylthio)methane
3561-67-9

bis(phenylthio)methane

C

1,2-bis(phenylthio)ethane
622-20-8

1,2-bis(phenylthio)ethane

D

diphenyldisulfane
882-33-7

diphenyldisulfane

E

lithium chloride

lithium chloride

Conditions
ConditionsYield
In tetrahydrofuran mixing reactants in THF at -78°C, slow warming to room temp. / further products; evapn. in vac., extn. with pentane, ether and finally acetone or CH2Cl2, concn., chromy. on Al2O3, purifn. by crystn., distn. or sublimation;A 27%
B 27%
C 38%
D 25%
E 98%
ferrocenium hexafluorophosphate

ferrocenium hexafluorophosphate

tetrabutylammonium dimethylaurate(I)
228118-52-3

tetrabutylammonium dimethylaurate(I)

A

ferrocene
102-54-5

ferrocene

Conditions
ConditionsYield
In tetrahydrofuran byproducts: CH4, C2H6; He-atmosphere; addn. of 1 equiv. of Cp2FePF6 to soln. of aurate at -196°C, warming to room temp.;A 94%
B 97%
In acetonitrile byproducts: CH4, C2H6; He-atmosphere; addn. of 1 equiv. of Cp2FePF6 to soln. of aurate at -196°C, warming to room temp.;A 96%
B 96%
[(η6-p-xylene)(η5-cyclopentadienyl)iron(II)](hexafluorophosphate)

[(η6-p-xylene)(η5-cyclopentadienyl)iron(II)](hexafluorophosphate)

acetonitrile
75-05-8

acetonitrile

ferrocene
102-54-5

ferrocene

Conditions
ConditionsYield
In acetonitrile byproducts: Fe(II), p-xylene; Irradiation (UV/VIS); a CH3CN soln. of Fe-compd. was degassed by bubbling with N2 for 10 min and irradiated with sunlight for 3 h 25 min at room temp.;; evapn. of the solvent and extn. the residue with cyclohexane; detected by NMR-expt.;;97%
In acetonitrile byproducts: Fe(II), p-xylene; Irradiation (UV/VIS); a CH3CN soln. of Fe-compd. was degassed by bubbling with N2 for 10 min and irradiated with an Oriel lamp for 3 h 25 min at room temp.;; evapn. of the solvent and extn. the residue with cyclohexane; detected by NMR-expt.;;93%
ferrocenium tetrakis(pentafluorophenyl)borate
135348-57-1

ferrocenium tetrakis(pentafluorophenyl)borate

Ti(N[tBu](3,5-Me2C6H3))3

Ti(N[tBu](3,5-Me2C6H3))3

A

ferrocene
102-54-5

ferrocene

B

[Ti(N[tBu](3,5-Me2C6H3))3][B(C6F5)4]

[Ti(N[tBu](3,5-Me2C6H3))3][B(C6F5)4]

Conditions
ConditionsYield
In diethyl ether for 0.5h; Inert atmosphere; Schlenk technique; Glovebox;A 80%
B 97%
cyclopentadienylthallium
34822-90-7

cyclopentadienylthallium

iron(III) chloride
7705-08-0

iron(III) chloride

ferrocene
102-54-5

ferrocene

Conditions
ConditionsYield
In tetrahydrofuran anhyd. FeCl3, boiling abs. THF, under exclusion of air; preparation of small amts.;;96%
lithiumferrocene
1271-15-4

lithiumferrocene

lead(II) chloride

lead(II) chloride

A

lead
7439-92-1

lead

B

ferrocene
102-54-5

ferrocene

Conditions
ConditionsYield
In diethyl ether byproducts: LiCl; Ar; to a suspn. of PbCl2 added a suspn. of FcLi, stirred for 2 h; ppt. (Pb) filtered, washed (H2O), dried, analyzed; Fc not isolated, detected by NMR;A 96%
B n/a
4,4'-bis((η6-phenoxy-η5-cyclopentadienyl)iron)biphenyl hexafluorophosphate

4,4'-bis((η6-phenoxy-η5-cyclopentadienyl)iron)biphenyl hexafluorophosphate

A

ferrocene
102-54-5

ferrocene

B

4,4'-diphenoxy-1,1'-biphenyl
2519-16-6

4,4'-diphenoxy-1,1'-biphenyl

Conditions
ConditionsYield
In dichloromethane; acetonitrile Irradiation (UV/VIS); addn. of diiron-complex dissolved in CH2Cl2/CH3CN to a photolysis tube, purging with N2 for 30 min, irradiation under intense visible light (Xenon lamp) for 4 h; concn. by evapn. under reduced pressure, column chromy., elution (hexane) gives yellow band of ferrocene, elution (hexane/CHCl3) gives benzene-compd., evapn. to dryness, elem. anal.;A n/a
B 96%
1,2-bis((η6-4-methylphenoxy-η5-cyclopentadienyl)iron)benzene hexafluorophosphate

1,2-bis((η6-4-methylphenoxy-η5-cyclopentadienyl)iron)benzene hexafluorophosphate

A

ferrocene
102-54-5

ferrocene

B

1,2-bis-(4-methylphenoxy)benzene
153287-98-0

1,2-bis-(4-methylphenoxy)benzene

Conditions
ConditionsYield
In dichloromethane; acetonitrile Irradiation (UV/VIS); addn. of diiron-complex dissolved in CH2Cl2/CH3CN to a photolysis tube, purging with N2 for 30 min, irradiation under intense visible light (Xenon lamp) for 4 h; concn. by evapn. under reduced pressure, column chromy., elution (hexane) gives yellow band of ferrocene, elution (hexane/CHCl3) gives benzene-compd., evapn. to dryness, elem. anal.;A n/a
B 96%
ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

(triphenylphosphane)gold(I) tert-butylthiolate
122711-31-3

(triphenylphosphane)gold(I) tert-butylthiolate

A

ferrocene
102-54-5

ferrocene

B

tetrakis(triphenylphosphane)bis(tert-butylthiolate)tetragold(I) tetrafluoroborate

tetrakis(triphenylphosphane)bis(tert-butylthiolate)tetragold(I) tetrafluoroborate

Conditions
ConditionsYield
In dichloromethane byproducts: (SC(CH3)3)2; N2, Fe:Au=0.136:0.276 molar ratio, Fe compd. added to a soln. of Au compd., stirred for 30 min; solvent evapd., residue washed (diethyl ether, benzene), dried (vac.), recrystd. (CH2Cl2, -5°C), org. phases evapd. to dryness, ferrocenesublimied (40°C, high vac.); elem. anal.;A n/a
B 96%
ferrocenium hexafluorophosphate

ferrocenium hexafluorophosphate

C6H3(C(CH2CH2CH2Si(CH3)2CH2OC6H4C(CH2CH2CH2Si(CH3)2CH2N3C2HC5H4FeC5H4C5H4FeC5H5)3)3)3

C6H3(C(CH2CH2CH2Si(CH3)2CH2OC6H4C(CH2CH2CH2Si(CH3)2CH2N3C2HC5H4FeC5H4C5H4FeC5H5)3)3)3

A

ferrocene
102-54-5

ferrocene

B

C6H3(C(CH2CH2CH2Si(CH3)2CH2OC6H4C(CH2CH2CH2Si(CH3)2CH2N3C2HC5H4FeC5H4C5H4FeC5H5)3)3)3(27+)*27PF6(1-)

C6H3(C(CH2CH2CH2Si(CH3)2CH2OC6H4C(CH2CH2CH2Si(CH3)2CH2N3C2HC5H4FeC5H4C5H4FeC5H5)3)3)3(27+)*27PF6(1-)

Conditions
ConditionsYield
In dichloromethane byproducts: ferrocene; 27 equivs. of (C5H5)Fe(C5H5)(PF6) in CH2Cl2 added to dendrimer complex in CH2Cl2 at room temp.; allowed to stir under N2 for 1 h at room temp.; Et2O added dropwise; filtered under N2 on Celite; dried in vac.; elem. anal.;A 96%
B 66.3%
{fc-P(C6H5)2CH2C6H5}OH

{fc-P(C6H5)2CH2C6H5}OH

A

ferrocene
102-54-5

ferrocene

B

(diphenylphosphinoyl)ferrocene

(diphenylphosphinoyl)ferrocene

C

fc-PO(C6H5)(CH2C6H5)

fc-PO(C6H5)(CH2C6H5)

D

toluene
108-88-3

toluene

E

benzene
71-43-2

benzene

Conditions
ConditionsYield
With potassium chloride In 1,2-dimethoxyethane; water ratio H2O:(CH2OCH3)2 = 50:50 %, 0.4 M KCl, boiling; not isolated;A n/a
B 35.9%
C n/a
D 95.3%
E 3.9%
With KCl In 1,2-dimethoxyethane; water ratio H2O:(CH2OCH3)2 = 50:50 %, 0.4 M KCl, boiling; not isolated;A n/a
B 35.9%
C n/a
D 95.3%
E 3.9%
ferrocenium hexafluorophosphate

ferrocenium hexafluorophosphate

di(t-butylimido)di(2,4,6-trimethylphenyl)rhenium(VI)
126572-58-5

di(t-butylimido)di(2,4,6-trimethylphenyl)rhenium(VI)

A

ferrocene
102-54-5

ferrocene

B

di(t-butylimido)di(2,4,6-trimethylphenyl)rhenium(VII) hexafluorophosphate

di(t-butylimido)di(2,4,6-trimethylphenyl)rhenium(VII) hexafluorophosphate

Conditions
ConditionsYield
In tetrahydrofuran absence of air; stirring (1 h); solvent removal (vac.), washing (hexane), crystn. (THF/Et2O); elem. anal.;A n/a
B 95%
1,2-bis((η6-phenoxy-η5-cyclopentadienyl)iron)benzene hexafluorophosphate

1,2-bis((η6-phenoxy-η5-cyclopentadienyl)iron)benzene hexafluorophosphate

A

ferrocene
102-54-5

ferrocene

B

1,2-diphenoxybenzene
3379-37-1

1,2-diphenoxybenzene

Conditions
ConditionsYield
In dichloromethane; acetonitrile Irradiation (UV/VIS); addn. of diiron-complex dissolved in CH2Cl2/CH3CN to a photolysis tube, purging with N2 for 30 min, irradiation under intense visible light (Xenon lamp) for 4 h; concn. (vac.), column chromy., elution (hexane) gives yellow band of ferrocene, elution (hexane/CHCl3) gives benzene-compd., evapn. to dryness, elem. anal.;A n/a
B 95%
ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

bis[(1,2-bis(dimethylphosphino)ethane)(η(5)-methylcyclopentadienyl)manganese(I)](μ-2,3-diphenylbutadien-1,4-diylidene)
223424-75-7

bis[(1,2-bis(dimethylphosphino)ethane)(η(5)-methylcyclopentadienyl)manganese(I)](μ-2,3-diphenylbutadien-1,4-diylidene)

A

ferrocene
102-54-5

ferrocene

B

bis[(1,2-bis(dimethylphopshino)ethane)(η(5)-methylcyclopentadienyl)manganese(III)](μ-2,3-diphenylbut-2-en-1,4-diylidyne) bis(tetrafluoroborate)

bis[(1,2-bis(dimethylphopshino)ethane)(η(5)-methylcyclopentadienyl)manganese(III)](μ-2,3-diphenylbut-2-en-1,4-diylidyne) bis(tetrafluoroborate)

Conditions
ConditionsYield
In dichloromethane N2-atmosphere; filtering, concg., pptn. on Et2O addn.; collecting, washing (Et2O), drying (vac.), repptn., recrystn. (CH2Cl2, room temp.); elem. anal.;A n/a
B 95%
(η(5)-2-cyclopentadienyl-2-indenyl-propane)Rh(1,5-cyclooctadiene)
209473-49-4

(η(5)-2-cyclopentadienyl-2-indenyl-propane)Rh(1,5-cyclooctadiene)

[(cyclopentadienyl)Fe(fluorene)]PF6
232282-91-6

[(cyclopentadienyl)Fe(fluorene)]PF6

A

ferrocene
102-54-5

ferrocene

B

[Rh(cyclooctadiene)(η5-cyclopentadienyl)C(CH3)2(η5-indenyl)Fe(η5-cyclopentadienyl)]
329985-01-5, 912572-47-5

[Rh(cyclooctadiene)(η5-cyclopentadienyl)C(CH3)2(η5-indenyl)Fe(η5-cyclopentadienyl)]

Conditions
ConditionsYield
With BuLi In tetrahydrofuran byproducts: fluorene; (N2); (COD)Rh(Cp)C(CH3)2(C9H6) deprotonated with BuLi in THF; soln. prepared from (CpFe(fluorene))PF6 and BuLi added at 0 °C after 1 h; refluxed for 16 h; solvend removed; extracted by pentane/diethyl ether (1:1); chromy.(pentane/diethyl ether); elem. anal.;A n/a
B 95%
ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

(methyldiphenylphosphane)gold(I) tetr-butylthiolate
1002113-69-0

(methyldiphenylphosphane)gold(I) tetr-butylthiolate

A

ferrocene
102-54-5

ferrocene

B

tetrakis(methyldiphenylphosphane)bis(tert-butylthiolate)tetragold(I) tetrafluoroborate

tetrakis(methyldiphenylphosphane)bis(tert-butylthiolate)tetragold(I) tetrafluoroborate

Conditions
ConditionsYield
In dichloromethane byproducts: (SC(CH3)3)2; N2, Fe:Au=0.136:0.276 molar ratio, Fe compd. added to a soln. of Au compd., stirred for 30 min; solvent evapd., residue washed (diethyl ether, benzene), dried (vac.), recrystd. (CH2Cl2, -5°C), org. phases evapd. to dryness, ferrocenesublimied (40°C, high vac.); elem. anal.;A n/a
B 95%
ferrocenium hexafluorophosphate

ferrocenium hexafluorophosphate

W6S8(P(C2H5)3)6

W6S8(P(C2H5)3)6

A

ferrocene
102-54-5

ferrocene

B

W6S8(P(C2H5)3)6(1+)*PF6(1-)=W6S8(P(C2H5)3)6PF6

W6S8(P(C2H5)3)6(1+)*PF6(1-)=W6S8(P(C2H5)3)6PF6

Conditions
ConditionsYield
In benzene W-cluster was dissolved in benzene in Schlenk flask, soln. of Fe-complexwas added, stirred for 1 h; after 2 d filtered, washed with Et2O, dried;A n/a
B 95%
In dichloromethane W-cluster was dissolved in CH2Cl2 in Schlenk flask, soln. of Fe-complex in CH2Cl2 was added, stirred for 30 min; solvent was removed under vac. washed with benzene and Et2O;A n/a
B 85%
1,1'-dibromoferrocene
1293-65-8

1,1'-dibromoferrocene

water
7732-18-5

water

A

ferrocene
102-54-5

ferrocene

B

bromoferrocene
1273-73-0

bromoferrocene

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran under N2; n-BuLi in THF added dropwise at -35°C to soln. of Fe complex in THF; stirred at -35°C for 1 h; H2O added dropwise; warmed to room temp. over 1 h; extd. with Et2O; org. layer collected; washed with H2O; dried (Na2SO4); solvent removed under reduced pressure; bromoferrocene contaminated withferrocene (10%);A n/a
B 95%
ferrocenium trifluoromethanesulfonate

ferrocenium trifluoromethanesulfonate

A

ferrocene
102-54-5

ferrocene

B

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

Conditions
ConditionsYield
With C26H46ClO3Ru2S2(1+)*CF3O3S(1-); hydrogen In water at 20℃; under 760.051 Torr; for 1.2h; Catalytic behavior; Temperature; Reagent/catalyst; Inert atmosphere; Schlenk technique;A 95%
B n/a
With [(pentamethylcyclopentadienyl)Ru{PhP(C6H4-o-S)2}Ru(pentamethylcyclopentadienyl)](OTf)2; hydrogen In water at 20℃; under 760.051 Torr; for 20h;A 87%
B 86%
With [η5-C5Me5Ru(μ-SiPr)2Ru(OH2)-η5-C5Me5](OTf)2; hydrogen In methanol at 20℃; under 760.051 Torr; for 1.4h; Temperature; Reagent/catalyst; Solvent; Pressure; Schlenk technique;
ferrocenium hexafluorophosphate

ferrocenium hexafluorophosphate

ferrocene
102-54-5

ferrocene

Conditions
ConditionsYield
With tetramethylpiperidine; H2; Cp*Ru(dppf)H In acetone (Ar);; concn., extn. (hexanes);94%
With 1,7-dilithio-m-carborane In cyclohexane byproducts: LiPF6, m-carborane; (N2 or Ar); heated at 80°C for 24 h; quenched with wet n-hexane, passed through silica gel, washed (ether), the org. portions combined, evapd. (vac.), flash-chromd. (silica gel, n-hexane);49%
With sodium benzotriazolide In tetrahydrofuran at 20°C;
ferrocenium(III) tetrafluoroborate
1282-37-7

ferrocenium(III) tetrafluoroborate

Cp2Ta{(μ-CH2)2}CoCp

Cp2Ta{(μ-CH2)2}CoCp

A

ferrocene
102-54-5

ferrocene

B

{Cp2Ta(μ-CH2)2Co(CH3CN)Cp}(1+)BF4(1-)*CH3CN

{Cp2Ta(μ-CH2)2Co(CH3CN)Cp}(1+)BF4(1-)*CH3CN

Conditions
ConditionsYield
In acetonitrile 20 °C; variable temp. NMR;A n/a
B 94%
1,3-bis((η6-phenoxy-η5-cyclopentadienyl)iron)benzene hexafluorophosphate

1,3-bis((η6-phenoxy-η5-cyclopentadienyl)iron)benzene hexafluorophosphate

A

ferrocene
102-54-5

ferrocene

B

1,3-diphenoxybenzene
3379-38-2

1,3-diphenoxybenzene

Conditions
ConditionsYield
In dichloromethane; acetonitrile Irradiation (UV/VIS); addn. of diiron-complex dissolved in CH2Cl2/CH3CN to a photolysis tube, purging with N2 for 30 min, irradiation under intense visible light (Xenon lamp) for 4 h; concn. by evapn. under reduced pressure, column chromy., elution (hexane) gives yellow band of ferrocene, elution (hexane/CHCl3) gives benzene-compd., evapn. to dryness, elem. anal.;A n/a
B 94%
ferrocene
102-54-5

ferrocene

phenyl isocyanate
103-71-9

phenyl isocyanate

N-phenylferrocenecarboxamide

N-phenylferrocenecarboxamide

Conditions
ConditionsYield
With trifluorormethanesulfonic acid at 25℃; for 8h; Reagent/catalyst; Temperature; Inert atmosphere;100%
With aluminium trichloride25%
With AlCl325%
aluminium trichloride In carbon disulfide
ferrocene
102-54-5

ferrocene

ferricinium chloroferrate

ferricinium chloroferrate

Conditions
ConditionsYield
With hydrogenchloride; oxygen; iron(III) chloride In diethyl ether passing O2 through mixt. of ferrocene in ether and FeCl3 in aq. HCl;;100%
With FeCl3; O2; HCl In diethyl ether passing O2 through mixt. of ferrocene in ether and FeCl3 in aq. HCl;;100%
With sulfuryl dichloride In benzene in boiling benzene, equimolar amt. of ferrocene and SO2Cl2;;97%
ferrocene
102-54-5

ferrocene

β-cyclodextrin decahydrate

β-cyclodextrin decahydrate

ferrocene, β-cyclodextrin complex

ferrocene, β-cyclodextrin complex

Conditions
ConditionsYield
In water molar ratio cyclodextrin : ferrocene = 1:4, addn. of crystals of ferrocene to an aq. soln. of cyclodextrin at 60°C with stirring; washed with water, dried in vac., washed with THF, recrystn. from water or aq. alcohol; elem. anal.;100%
In ethanol; water molar ratio cyclodextrin : ferrocene = 2:1, an aq. alcohol soln. of cyclodextrin (40% ethanol) was mixed with an aq. alcohol soln. of ferrocene (60% ethanol); addn. of water and/or partial removal of ethanol by evapn.; elem. anal.;85%
In ethanol; water molar ratio cyclodextrin : ferrocene = 1:1, addn. of aq. soln. of cyclodextrin to an alcohol soln. of ferrocene with stirring and heating; elem. anal.;56%
In ethanol; water molar ratio cyclodextrin : ferrocene = 1:1, addn. of aq. soln. of cyclodextrin to an alcohol soln. of ferrocene with stirring and heating; elem. anal.;36%
ferrocene
102-54-5

ferrocene

[Cu((NCH2CH2)3(CH(CH3)2)2(CH2C6H2(O)(C(CH3)3)2))OSO2CF3](1+)

[Cu((NCH2CH2)3(CH(CH3)2)2(CH2C6H2(O)(C(CH3)3)2))OSO2CF3](1+)

A

ferrocenium
12125-80-3

ferrocenium

B

[Cu((NCH2CH2)3(CH(CH3)2)2(CH2C6H2(O)(C(CH3)3)2))OSO2CF3]

[Cu((NCH2CH2)3(CH(CH3)2)2(CH2C6H2(O)(C(CH3)3)2))OSO2CF3]

Conditions
ConditionsYield
In not given stoichiometric amt.;A n/a
B 100%
ferrocene
102-54-5

ferrocene

2-ferrocenyl-6-methyl-pyridin-4-yl nonaflate

2-ferrocenyl-6-methyl-pyridin-4-yl nonaflate

2-methyl-4,6-bisferrocenyl pyridine
152602-97-6

2-methyl-4,6-bisferrocenyl pyridine

Conditions
ConditionsYield
Stage #1: ferrocene With potassium tert-butylate In tetrahydrofuran Inert atmosphere; Schlenk technique;
Stage #2: With tert.-butyl lithium In tetrahydrofuran; pentane at -30℃; for 1h; Inert atmosphere;
Stage #3: 2-ferrocenyl-6-methyl-pyridin-4-yl nonaflate Further stages;
100%
ferrocene
102-54-5

ferrocene

3-diazonium-o-carborane tetrafluoroborate

3-diazonium-o-carborane tetrafluoroborate

C12H20B10Fe

C12H20B10Fe

Conditions
ConditionsYield
With eosin In acetonitrile at 20℃; for 2h; Inert atmosphere; Schlenk technique; Irradiation; regioselective reaction;100%
ferrocene
102-54-5

ferrocene

hydrogen fluoride
7664-39-3

hydrogen fluoride

phosphorus pentafluoride
7647-19-0, 874483-74-6

phosphorus pentafluoride

C10H11Fe(1+)*F6P(1-)

C10H11Fe(1+)*F6P(1-)

Conditions
ConditionsYield
at -196 - 20℃; Sealed tube;100%
ferrocene
102-54-5

ferrocene

2-methylimidazole
693-98-1

2-methylimidazole

[iron(II)(2-methylimidazolate)2]

[iron(II)(2-methylimidazolate)2]

Conditions
ConditionsYield
With 4,4'-bipyridine at 150℃; for 48h; Reagent/catalyst;100%
ferrocene
102-54-5

ferrocene

perfluoro-o-phenylenemercury trimer
18734-63-9

perfluoro-o-phenylenemercury trimer

2(HgC6F4)3*Fe(C5H5)2

2(HgC6F4)3*Fe(C5H5)2

Conditions
ConditionsYield
In dichloromethane soln. of (HgC6F5)3 (0.096 mol) in CH2Cl2 mixed with soln. ferrocene (0.538 mol) in CH2Cl2; crystd. by slow evapn. of solvent; crystals washed (hexane); elem. anal.;99%
In dichloromethane no react. in CH2Cl2 soln.; (199)Hg NMR;0%
hexafluorophosphoric acid

hexafluorophosphoric acid

ferrocene
102-54-5

ferrocene

pentamethylbenzene,
700-12-9

pentamethylbenzene,

{(Cp)iron(II)(η6-pentamethylbenzene)}(PF6)
112596-54-0

{(Cp)iron(II)(η6-pentamethylbenzene)}(PF6)

Conditions
ConditionsYield
With aluminium trichloride; aluminium In neat (no solvent) ferrocene, Al-powder and AlCl3 are ground in a mortar, the arene is added and mixt. is reground, rapidly transferred to a microwave app. (react. time 3 min) and heated; complex is isolated by adding water and pptg. with HPF6 from the aq. soln.;99%
With aluminium trichloride; water; aluminium In not given treatment of ferrocene with benzene deriv. in presence of aluminium, AlCl3 and 1 equiv. of water at 100°C; Hamon J.R., Astruc D., MichaudP., J. Am. Chem. Soc., 1981, 103, 758-766; treatment with aq. ammonia, treatment with HPF6;
ferricenium tetrakis(pentafluorophenyl)borate
135348-57-1

ferricenium tetrakis(pentafluorophenyl)borate

Ti(N[tBu](3,5-Me2C6H3))3

Ti(N[tBu](3,5-Me2C6H3))3

A

ferrocene
102-54-5

ferrocene

B

[Ti(N[tBu](3,5-Me2C6H3))3][B(C6F5)4]

[Ti(N[tBu](3,5-Me2C6H3))3][B(C6F5)4]

Conditions
ConditionsYield
In diethyl ether for 0.5h; Inert atmosphere; Schlenk technique; Glovebox;A 80%
B 97%
ferrocene
102-54-5

ferrocene

benzaldehyde
100-52-7

benzaldehyde

Ferrocenyl(phenyl)carbenium perchlorate

Ferrocenyl(phenyl)carbenium perchlorate

Conditions
ConditionsYield
With trichlorophosphate In perchloric acid; diethyl ether aq. HClO4 addn. to ferrocene, carbonyl compd. and POCl3 (room temp., over 2 h), addn. of ether, standing (15 h), pptn.; collection (filtration), washing (ether); elem. anal.;99%
ferrocene
102-54-5

ferrocene

benzoyl chloride
98-88-4

benzoyl chloride

1,1’-dibenzoylferrocene
12180-80-2, 32983-90-7

1,1’-dibenzoylferrocene

Conditions
ConditionsYield
With aluminium chloride In dichloromethane ferrocene (1.0 equiv.) added to a stirred suspension of benzoyl chloride(2.2 equiv.) and aluminium chloride (2.2 equiv.) in dichloromethane, st irred at room temp. overnight (16 h); washed with water, organic layer passed through a plug of alumina, washed with chloroform, washings concentrated in vacuo, crude product purified by flash column chromy. on silica gel (TLC Rf 0.26 (1:1 ether-hexane)), elem. anal.;99%
With aluminium trichloride In dichloromethane to suspn. of AlCl3 in CH2Cl2 ligand was added, soln. of Fe-complex in CH2Cl2 was added, stirred for 3 ds at room temp. under Ar; aq. soln. of NaHCO3 was added, extd. with CH2Cl2, washed with aq. NaHCO3, dried over MgSO4, concd. under reduced pressure, column chromy. on silica gel with pentane-Et2O; elem. anal.;87%
With aluminium trichloride; benzoyl chloride In dichloromethane soln. of C6H5COCl and AlCl3 in dry CH2Cl2 was added dropwise over a period of 1 h to a stirred soln. of ferrocene in dry CH2Cl2; soln. was refluxed for 30 min, hydrolized with 0.1 M HCl, product worked up; solid chromd. on alumina using benzene, following by ether ewluant;86%
With aluminum (III) chloride In dichloromethane at 0℃; for 0.5h; Inert atmosphere; Schlenk technique;75%
With AlCl3 In dichloromethane
Indole-3-carboxaldehyde
487-89-8

Indole-3-carboxaldehyde

ferrocene
102-54-5

ferrocene

(C5H5FeC5H4CHC8H5NH)(1+)*ClO4(1-)=(C5H5FeC5H4CHC8H5NH)ClO4

(C5H5FeC5H4CHC8H5NH)(1+)*ClO4(1-)=(C5H5FeC5H4CHC8H5NH)ClO4

Conditions
ConditionsYield
With trichlorophosphate In perchloric acid; diethyl ether aq. HClO4 addn. to ferrocene, carbonyl compd. and POCl3 (room temp., over 1 h), addn. of ether, standing (15 h), pptn.; collection (filtration), washing (ether); elem. anal.;99%
ammonium hexafluorophosphate

ammonium hexafluorophosphate

ferrocene
102-54-5

ferrocene

<33>(1,3,5)-cyclophane
13821-31-3

<33>(1,3,5)-cyclophane

bis(η(5)-cyclopentadienyl)(η(6),η(6)-[3(3)](1,3,5)cyclophane)diiron(II,II) bis(hexafluorophosphate)

bis(η(5)-cyclopentadienyl)(η(6),η(6)-[3(3)](1,3,5)cyclophane)diiron(II,II) bis(hexafluorophosphate)

Conditions
ConditionsYield
With aluminium trichloride; aluminium In decalin Ar-atmosphere; heating cyclophane with excess of Fe-complex, AlCl3 and Al (160°C, 2 h), cooling in ice bath, washing aq. layer (Et2O), filtration, addn. of excess of aq. NH4PF6 (pptn.); filtration, drying (vac., room temp.); elem. anal.;99%
ferrocene
102-54-5

ferrocene

Co(C27H34N4O4)

Co(C27H34N4O4)

(C5H5)2Fe(1+)*Co(C27H34N4O4)(1-)=[(C5H5)2Fe][Co(C27H34N4O4)]
212846-49-6

(C5H5)2Fe(1+)*Co(C27H34N4O4)(1-)=[(C5H5)2Fe][Co(C27H34N4O4)]

Conditions
ConditionsYield
In cyclohexane excess Cp2Fe (pptn.); centrifugation;99%
ferrocene
102-54-5

ferrocene

Co(C27H32Cl2N4O4)

Co(C27H32Cl2N4O4)

(C5H5)2Fe(1+)*Co(C27H32Cl2N4O4)(1-)=[(C5H5)2Fe][Co(C27H32Cl2N4O4)]
212846-59-8

(C5H5)2Fe(1+)*Co(C27H32Cl2N4O4)(1-)=[(C5H5)2Fe][Co(C27H32Cl2N4O4)]

Conditions
ConditionsYield
In cyclohexane excess Cp2Fe (pptn.); centrifugation;99%
ferrocene
102-54-5

ferrocene

[Fe(η5-cyclopentadienyl)(η-benzene)]

[Fe(η5-cyclopentadienyl)(η-benzene)]

(η-C5H5)Fe(μ-η:η-C5H5)Fe(η-C5H5)

(η-C5H5)Fe(μ-η:η-C5H5)Fe(η-C5H5)

Conditions
ConditionsYield
In dichloromethane Irradiation (UV/VIS); irradiation (visible light, 250 W luminescence lamp), 0°C, 1 h, intense stirring; soln. concentrating in vacuum, residue washing repeatedly by petroleum ether, vacuum drying; elem. anal.;99%
ferrocene
102-54-5

ferrocene

mercury(II) trichloroacetate
15873-63-9, 20464-21-5

mercury(II) trichloroacetate

sodium chloride
7647-14-5

sodium chloride

decakis(chloridomercury(II))ferrocene

decakis(chloridomercury(II))ferrocene

Conditions
ConditionsYield
In methanol; diethyl ether; water addn. of soln. of ferocene (in Et2O) to soln. of Hg-salt (in MeOH), stirring (ambient temp., 15 - 30 min), pouring into ice H2O, satd. with NaCl, stirring (2 h); filtration, washing, (15 % aq. KI, satd. aq. NaCl, H2O, EtOH and ether),drying; elem. anal.;99%
In methanol; water 50°C; addn. of soln. of ferocene (in Et2O) to soln. of Hg-salt (in MeOH), stirring (ambient temp., 15 - 30 min), pouring into ice H2O, satd. with NaCl, stirring (2 h); filtration, washing, (15 % aq. KI, satd. aq. NaCl, H2O, EtOH and ether),drying; elem. anal.;99%
In methanol; water addn. of ferocene to soln. of Hg-salt (in MeOH), stirring (ambient temp., 15 - 30 min), pouring into ice H2O, satd. with NaCl, stirring (2 h); filtration, washing, (15 % aq. KI, satd. aq. NaCl, H2O, EtOH and ether),drying;99%
ferrocene
102-54-5

ferrocene

(E)-4,4-dimethyl-2-pentenoyl chloride
132278-01-4

(E)-4,4-dimethyl-2-pentenoyl chloride

E-1-ferrocenyl-4,4-dimethylpent-2-ene-1-one

E-1-ferrocenyl-4,4-dimethylpent-2-ene-1-one

Conditions
ConditionsYield
With AlCl3 In dichloromethane under N2; CH2Cl2 added with stirring to mixt. of Fe complex and AlCl3 (molar ratio 1:1); cooled to -78°C; soln. of t-BuCHCHC(O)Cl (1 equiv.) in CH2Cl2 added dropwise over 30 min; warmed slowly to room temp. over 20 min; quenched by dropwise addition of satd. aq. soln. of Na2S2O4; org. layer sepd.; washed with water and satd. aq. NaCl in air; dried (MgSO4); soln.filtered; volatiles removed in vac.; recrystd. from satd. soln. in hexa ne-Et2O at -30°C; elem. anal.;99%
ferrocene
102-54-5

ferrocene

2-Iodobenzoyl chloride
609-67-6

2-Iodobenzoyl chloride

(o-Iodobenzoyl)ferrocene
109800-02-4

(o-Iodobenzoyl)ferrocene

Conditions
ConditionsYield
With aluminum (III) chloride In dichloromethane at 0 - 20℃; for 0.25h; Friedel-Crafts Acylation; Inert atmosphere; Schlenk technique;99%
With aluminum (III) chloride In dichloromethane at 20℃; for 3h; Inert atmosphere;0.243 g
Friedel-Crafts Acylation;
ferrocene
102-54-5

ferrocene

bis(nonafluoro-tert-butyl) peroxide
26842-85-3

bis(nonafluoro-tert-butyl) peroxide

ferrocenium nonafluoro-tert-butoxide

ferrocenium nonafluoro-tert-butoxide

Conditions
ConditionsYield
at 20℃; Schlenk technique;99%
Schlenk technique; Inert atmosphere;99%
ferrocene
102-54-5

ferrocene

N-methyl-N-phenylformamide
93-61-8

N-methyl-N-phenylformamide

ferrocenecarboxaldehyde
12093-10-6

ferrocenecarboxaldehyde

Conditions
ConditionsYield
Stage #1: N-methyl-N-phenylformamide With trichlorophosphate at 0℃; for 0.25h;
Stage #2: ferrocene at 20℃; Inert atmosphere;
98%
With phosphorus oxychloride In neat (no solvent) anilide and P-compd. stirring at room temp. for 30 min, Fe-compd. addn.,mixt. stirring at room temp. for 3 d, quenching by pouring onto ice, aq . layer extn. after 2 h with Et2O, org. layer drying (MgSO4), vac. concn.; residue flash column chromy. (SiO2, petrol/E2O 7:3 to 5:5), recrystn. (hot petroleum);87%
With trichlorophosphate In neat (no solvent) Vilsmeyer formylation; double mol amt. of formylation mixt., few days at ambient temp.;;81%
ferrocene
102-54-5

ferrocene

propionic acid anhydride
123-62-6

propionic acid anhydride

propionylferrocene

propionylferrocene

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In dichloromethane ferrocene and 2 equivs. of acid anhydride suspended in CH2Cl2 and cooledto 0°C, boron trifluoride etherate added over 10 min, stirred at room temp. for 3 h; poured into ice H2O, sepd., the org. layer washed (satd. NaHCO3 soln.), dried (MgSO4), solvent-removed, flash-chromd. (SiO2, cyclohexane/EtOAc);98%
With aluminum (III) chloride In chloroform at 4 - 40℃; for 1h; Friedel-Crafts Acylation;87%
With polyphosphoric acid In propionic acid anhydride Ar-atmosphere; addn. of excess of anhydride to Fe-complex soln., addn. of polyphosphoric acid, heating to 100°C for 15 min; pouring into ice water, neutralization (aq. Na2CO3), extn. into ether, washing of org. phase (H2O), drying (MgSO4), filtration, concn. (vac.), chromy. (SiO2, ether/pentane=1:3);80%
butanoic acid anhydride
106-31-0

butanoic acid anhydride

ferrocene
102-54-5

ferrocene

1-butanoylferrocene

1-butanoylferrocene

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In dichloromethane ferrocene and 2 equivs. of acid anhydride suspended in CH2Cl2 and cooledto 0°C, boron trifluoride etherate added over 10 min, stirred at room temp. for 3 h; poured into ice H2O, sepd., the org. layer washed (satd. NaHCO3 soln.), dried (MgSO4), solvent-removed, flash-chromd. (SiO2, cyclohexane/EtOAc);obtained as oil;98%
With aluminum (III) chloride In chloroform at 4 - 40℃; for 1h; Friedel-Crafts Acylation;84%
With aluminum oxide In dichloromethane stirring (30 min); extraction (water, Et2O), chromy.;60%

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Evaluating Ferrocene (cas 102-54-5) ions and all-Ferrocene (cas 102-54-5) salts for electrochemical applications08/03/2019

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