121612-12-2Relevant academic research and scientific papers
tert-Butyl Nitrite Mediated Different Functionalizations of Internal Alkenes: Paths to Furoxans and Nitroalkenes
Mir, Bilal Ahmad,Singh, Sarangthem Joychandra,Kumar, Ritush,Patel, Bhisma K.
, p. 3801 - 3809 (2018)
tert-Butyl nitrite (TBN) reacts differently with various internal alkenes leading to interesting and useful products. Synthesis of 1,2,5-oxadiazole-N-oxides (furoxans) has been achieved from internal alkenes using tert-butyl nitrite (TBN), quinoline and K2S2O8. Under an identical reaction condition α,β-unsaturated carboxylic acids and cyclic and acyclic internal alkenes both afforded nitroalkenes as the sole product via decarboxylative and direct nitration path respectively. (Figure presented.).
