121682-56-2Relevant academic research and scientific papers
Scandium(III) perchlorate (Sc(ClO4)3). A novel catalyst in the α-C- and N-glycosylation reactions
Hachiya,Kobayashi
, p. 3319 - 3320 (2007/10/02)
In the presence of a catalytic amount of scandium(III) perchlorate (Sc(ClO4)3), 1-O-acetyl-2,3,5-tri-O-benzyl-β-D-ribofuranose reacted with trimethylsilylated nucleophiles to afford the corresponding α-D-ribofuranosides in high yield
Stereoselective 1,2-cis Glycosylation Reaction of 1-O-Acetylribose with Silylated Nucleophiles by the Promotion of a New Catalyst System
Mukaiyama, Teruaki,Shimpuku, Tetsuro,Takashima, Tohru,Kobayashi, Shu
, p. 145 - 148 (2007/10/02)
1,2-cis-Ribofuranosides are stereoselectively prepared in high yields by the reaction of 1-O-acetyl-β-D-ribose with silylated nucleophiles by the promotion of a new catalyst system, the combined use of a catalytic amount of tin(IV) chloride and tin(II) tr
