17510-46-2

Basic information

• Product Name: (2,2-DIMETHYL-1-METHYLENEPROPOXY)TRIMETHYLSILANE
• Synonyms: (2,2-DIMETHYL-1-METHYLENEPROPOXY)TRIMETHYLSILANE;(1-TERT-BUTYLVINYLOXY)TRIMETHYLSILANE;PINACOLONE TRIMETHYLSILYL ENOL ETHER;T-BUTYLVINYLOXYTRIMETHYLSILANE;TERT-BUTYLVINYLOXYTRIMETHYLSILANE;(2,2-Dimethyl-1-methylenepropoxy)trimethylsilane, 3,3-Dimethyl-2-trimethylsiloxy-1-butene, Pinacolone enol trimethylsilyl ether;(1-tert-Butylvinyloxy)triMethylsilane 98%
• CAS NO: 17510-46-2
• Molecular Formula: C₉H₂₀OSi
• Molecular Weight: 172.34
• Mol File: 17510-46-2.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 140-142 °C(lit.)
• Flash Point: 76 °F
• Appearance: /
• Density: 0.798 g/mL at 25 °C(lit.)
• Vapor Pressure: 6.997mmHg at 25°C
• Refractive Index: n20/D 1.409(lit.)
• BRN: 2204704
• CAS DataBase Reference: (2,2-DIMETHYL-1-METHYLENEPROPOXY)TRIMETHYLSILANE(CAS DataBase Reference)
• NIST Chemistry Reference: (2,2-DIMETHYL-1-METHYLENEPROPOXY)TRIMETHYLSILANE(17510-46-2)
• EPA Substance Registry System: (2,2-DIMETHYL-1-METHYLENEPROPOXY)TRIMETHYLSILANE(17510-46-2)

Safety Data

• Hazard Codes: Xi
• Statements: 10-36/37/38
• Safety Statements: 26-36
• RIDADR: UN 1993 3/PG 3
• WGK Germany: 3
• F: 10-21
• HazardClass: 3.2
• PackingGroup: III
• Hazardous Substances Data: 17510-46-2(Hazardous Substances Data)

Usage

Uses

(1-tert-Butylvinyloxy)trimethylsilane ((2,2-Dimethyl-1-methylenepropoxy)trimethylsilane) may be used in the synthesis of cis-3,3-dimethyl-1-(6-phenethyl-3,6-dihydro-2H-pyran-2-yl)butan-2-one.

General Description

(1-tert-Butylvinyloxy)trimethylsilane is a silyl enol. It belongs to organosilicone class of compounds. Enthalpy of vaporization of (1-tert-Butylvinyloxy)trimethylsilane at boiling point has been reported.

InChI:InChI=1/C9H20OSi/c1-8(9(2,3)4)10-11(5,6)7/h1H2,2-7H3

Upstream product

• 75-97-8 3,3-dimethyl-butan-2-one 
• 10416-59-8 N,O-bis-(trimethylsilyl)-acetamide 

Downstream Products

• 624-95-3 3,3-dimethylbutanol 
• 37471-41-3 3,3-dimethyl-1-(phenylthio)butan-2-one 
• 83467-62-3 C₃₂H₃₂O₈ 
• 6721-67-1 tert-butyl benzyl ketone 
• 93836-20-5 2-(2,3,5-tri-O-benzyl-α-D-ribofuranosyl)acetophenone 
• 110874-50-5 (5S*,6R*)-2,2,6-Trimethyl-5-<(2,4,6-trimethylphenyl)thio>-3-octanone 
• 110903-55-4 (5R*,6R*)-2,2,6-Trimethyl-5-<(2,4,6-trimethylphenyl)thio>-3-octanone 
• 420-56-4 trimethylsilyl fluoride 
• 84224-47-5 3,3-dimethylbuten-2-yl nonaflate 
• 141377-54-0 2-nitro-1-phenylethan-1-ol 
• 42052-52-8 1-hydroxy-4,4-dimethyl-1-phenylpentan-3-one 
• 84896-29-7 4,4-dimethyl-1-phenyl-1-((trimethylsilyl)oxy)pentan-3-one 
• 155112-29-1 1-Nitro-2-phenyl-2-<(trimethylsilyl)oxy>-1-ethane 
• 65651-67-4 1-cyclohexyl-1-hydroxy-4,4-dimethylpentan-3-one 

Relevant articles and documents

SUR L'OBTENTION HAUTEMENT REGIO- ET STEREOSELECTIVED'ENOXYSILANES PAR ACTION DU BIS(TRIMETHYLSILYL)ACETAMIDE EN MILIEU HMPT SUR LESS DERIVES CARBONYLES ENOLISABLES

The authors describe a new and general method for the preparation of enoxysilanes by silylation of enolizable aldehydes and ketones by use of bis(trimethylsilyl)acetamide in HMPT, in the presence of very small quantities of sodium metal(or another basic a