121695-95-2

Upstream product

• 4039-32-1 lithium hexamethyldisilazane 
• 100-47-0 benzonitrile 
• 40654-28-2 C₁₃H₂₃N₂Si₂^(1-)*Li⁽¹⁺⁾ 
• 1079-66-9 chloro-diphenylphosphine 

Downstream Products

• 121711-35-1 1,5,5-tris(trimethylsilyl)-2,2,4-triphenylbenzamidinyl-2-phosphazene 
• 830321-85-2 ((CH₃)3Si)2NC(C₆H₅)NP(C₆H₅)2NSi(CH₃)3 
• 325969-66-2 cis-Mn(CO)4Br((Ph₂PN)C(Ph)[N(SiMe₃)2]) 
• 197446-49-4 [NiBr₂((C₆H₅)2PNHC(C₆H₅)NH)] 
• 188885-93-0 [Mo(CO)4(P(C₆H₅)2NHC(C₆H₅)N(Si(CH₃)3))]*H₂O 
• 166445-53-0 [Cr(CO)4(P(C₆H₅)2NHC(C₆H₅)N(Si(CH₃)3))] 
• 166445-53-0 (CO)4Cr((C₆H₅)2PNH)C(C₆H₅)(NSi(CH₃)3) 

Relevant academic research and scientific papers

Synthesis and Structure of an Unusual Molybdenum Heterocycle by Substitution of a Phenyl Ring in ortho-Position

The new ligand (Me3Si)2NC(Ph)NP(Ph)2N(SiMe3) (1) reacts with MoOCl4 to yield the green metallacycle 4. 4 was characterized by X-ray diffraction.Crystals of 4 are monoclinic, space group P21/n with a = 1061.2(10), b = 1590.5(10), c = 1737.4(20) pm, β = 104.84(7) deg and Z = 4.Mo is coordinated octahedrally by two nitrogens of the bifunctional ligand, by one oxygen and three chlorine atoms.The ligand undergoes cyclization, a bond being formed between N and one phenylic o-position. - Keywords: X-Ray, Molybdenum, Heterocycle, Phosphorus-Nitrogen Compound