1217271-19-6

Basic information

• Product Name: [(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)(benzyl)(NH(p-tolyl))]
• CAS NO: 1217271-19-6
• Molecular Weight: 858.091
• Mol File: 1217271-19-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)(benzyl)(NH(p-tolyl))](CAS DataBase Reference)
• NIST Chemistry Reference: [(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)(benzyl)(NH(p-tolyl))](1217271-19-6)
• EPA Substance Registry System: [(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)(benzyl)(NH(p-tolyl))](1217271-19-6)

Safety Data

• Hazardous Substances Data: 1217271-19-6(Hazardous Substances Data)

Upstream product

• 12150-46-8 1,1'-bis-(diphenylphosphino)ferrocene 
• 186340-23-8 [(1,5-cyclooctadiene)Pd(benzyl)Cl] 

Relevant articles and documents

C(sp3)-N bond-forming reductive elimination of amines: Reactions of bisphosphine-ligated benzylpalladium(II) diarylamido complexes

(Chemical Equation Presented) A rare event: The benzylpalladium amido complex 1 (Ar= napthyl) was used to study the mechanism of an unusual reductive elimination of amines (see scheme). The observed inversion of configuration is proposed to result from dissociation of the amido ligand, followed by nucleophilic attack on the benzylic carbon atom. binap = 2,2′- bis(diphenylphosphanyl)-1,1′-binaphthyl, dppf=1,1′- bis(diphenylphosphanyl)ferrocene.