1217438-38-4

Basic information

• Product Name: 1,1-diphenylpropan-2-one O-pentafluorobenzoyl oxime
• CAS NO: 1217438-38-4
• Molecular Weight: 419.351
• Mol File: 1217438-38-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,1-diphenylpropan-2-one O-pentafluorobenzoyl oxime(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1-diphenylpropan-2-one O-pentafluorobenzoyl oxime(1217438-38-4)
• EPA Substance Registry System: 1,1-diphenylpropan-2-one O-pentafluorobenzoyl oxime(1217438-38-4)

Safety Data

• Hazardous Substances Data: 1217438-38-4(Hazardous Substances Data)

Upstream product

• 6337-69-5 1,1-Diphenyl-2-propanone Oxime 
• 2251-50-5 pentafluorobenzoylchloride 

Downstream Products

• 1217438-48-6 [(C₆H₅CO₂)Pd(PCy₃)2(NC(CH₃)CH(C₆H₅)2)] 
• 4757-69-1 2-methyl-3-phenyl-1H-indole 

Relevant articles and documents

Palladium-catalyzed amination of aromatic C-H bonds with oxime esters

"Chemical equation presented" We report a conceptually new approach to the direct amination of aromatic C-H bonds. In this process, an oxime ester function reacts with an aromatic C-H bond under redox-neutral conditions to form, in the case studied, an indole product. These reactions occur with relatively low catalyst loading (1 mol %) by a mechanism that appears to involve an unusual initial oxidative addition of an N-O bond to a Pd(0) species. The Pd(II) complex from oxidative addition of the N-X bond has been isolated for the first time, and evidence for the intermediacy of such oxidative addition products in the catalytic reaction has been gained.