121757-32-2

Basic information

• Product Name: Methyl 2,2-dimethyl-5-(2,2-dimethyltetrahydro-3-(methoxycarbonyl)furan-5-ylidene)tetrahydro-3-furanacetate
• Synonyms: Methyl 2,2-dimethyl-5-(2,2-dimethyltetrahydro-3-(methoxycarbonyl)furan-5-ylidene)tetrahydro-3-furanacetate
• CAS NO: 121757-32-2
• Molecular Weight: 340.417
• Mol File: 121757-32-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Methyl 2,2-dimethyl-5-(2,2-dimethyltetrahydro-3-(methoxycarbonyl)furan-5-ylidene)tetrahydro-3-furanacetate(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl 2,2-dimethyl-5-(2,2-dimethyltetrahydro-3-(methoxycarbonyl)furan-5-ylidene)tetrahydro-3-furanacetate(121757-32-2)
• EPA Substance Registry System: Methyl 2,2-dimethyl-5-(2,2-dimethyltetrahydro-3-(methoxycarbonyl)furan-5-ylidene)tetrahydro-3-furanacetate(121757-32-2)

Safety Data

• Hazardous Substances Data: 121757-32-2(Hazardous Substances Data)

Upstream product

• 27830-36-0 methyl (2,2-dimethyl-3-oxocyclobutyl)acetate 

Relevant articles and documents

Mechanism and Synthetic Applications of the Photochemical Generation and X-H Insertion Reactions of Oxacarbenes

A kinetic study of the photochemical ring expansion of cyclobutanones to oxacarbenes has shown that, in the presence of alcohol, the oxacarbene is generated irreversibly.Substrates for the intramolecular versions of the oxacarbene generation-insertion sequence (heteroalkylcyclobutanones) were prepared by an intramolecular -Baeyer-Villiger sequence.These have been used to form 5-, 6-, 7-, and 8-membered nitrogen, oxygen, and sulfur bicyclic ring systems.