27830-36-0

Basic information

• Product Name: methyl (2,2-dimethyl-3-oxocyclobutyl)acetate
• Synonyms: methyl (2,2-dimethyl-3-oxocyclobutyl)acetate
• CAS NO: 27830-36-0
• Molecular Weight: 170.208
• Mol File: 27830-36-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl (2,2-dimethyl-3-oxocyclobutyl)acetate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (2,2-dimethyl-3-oxocyclobutyl)acetate(27830-36-0)
• EPA Substance Registry System: methyl (2,2-dimethyl-3-oxocyclobutyl)acetate(27830-36-0)

Safety Data

• Hazardous Substances Data: 27830-36-0(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 

Downstream Products

• 924-50-5 Methyl 3,3-dimethylacrylate 
• 20602-89-5 (2,2-Dimethyl-cyclopropyl)-essigsaeuremethylester 
• 113371-55-4 Methyl (3R^*,5S^*)-5-methoxy-2,2-dimethyltetrahydro-3-furanacetate 
• 113371-55-4 Methyl (3R^*,5R^*)-5-methoxy-2,2-dimethyltetrahydro-3-furanacetate 
• 113371-57-6 (5-Benzyloxy-2,2-dimethyl-tetrahydro-furan-3-yl)-acetic acid methyl ester 
• 113371-63-4 (2,2-Dimethyl-5-phenoxy-tetrahydro-furan-3-yl)-acetic acid methyl ester 
• 113371-59-8 (5-Cyclohexyloxy-2,2-dimethyl-tetrahydro-furan-3-yl)-acetic acid methyl ester 
• 38306-10-4 methyl 2-(2,2-dimethyl-5-oxotetrahydrofuran-3-yl)acetate 
• 121757-31-1 Methyl 2,2-dimethyl-4,5-dihydro-3-furanacetate 
• 121757-32-2 Methyl 2,2-dimethyl-5-(2,2-dimethyltetrahydro-3-(methoxycarbonyl)furan-5-ylidene)tetrahydro-3-furanacetate 

Relevant articles and documents

Photochemistry of Substituted Benzoylformate Esters. A Convenient Method for the Photochemical Oxidation of Alcohols

The production of aldehydes and ketones via photochemical hydrogen atom transfer in substituted benzoylformate esters of primary and secondary alcohols has been investigated.Substituent effect studies have shown that (2,4-dimethoxybenzoyl)formate (DMBF) esters give superior performance.A divergence in the byproducts derived from the ester group (the benzaldehyde (and presumably CO) or the benzoic acid (and presumably CO2)) is observed depending on the presence of oxygen.A mechanistic rationale for the benzoic acid has been advanced based on the known trapping of intermediate 1,4-biradicals by oxygen followed by fragmentation.