121794-95-4

Basic information

• Product Name: (S)-1-(benzyloxy)pent-4-en-2-amine
• Synonyms: (S)-1-(benzyloxy)pent-4-en-2-amine
• CAS NO: 121794-95-4
• Molecular Weight: 191.273
• Mol File: 121794-95-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (S)-1-(benzyloxy)pent-4-en-2-amine(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-1-(benzyloxy)pent-4-en-2-amine(121794-95-4)
• EPA Substance Registry System: (S)-1-(benzyloxy)pent-4-en-2-amine(121794-95-4)

Safety Data

• Hazardous Substances Data: 121794-95-4(Hazardous Substances Data)

Upstream product

• 1201635-94-0 1-{[(S)-2-azidopent-4-enyloxy]methyl} benzene 
• 910545-65-2 (1R,3R,4S)-3-allyl-3-amino-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one 
• 60656-87-3 benzyloxyacetoaldehyde 
• 115352-39-1 (2R)-1-benzyloxy-2-hydroxy-pent-4-yne 
• 14618-80-5 (R)-benzyl glycidol 
• 58931-16-1 (R)-1-benzyloxypent-4-en-2-ol 

Downstream Products

• 51-35-4 4R-4-hydroxyproline 
• 121794-98-7 (2S,4R)-4-Benzoyloxy-2-benzyloxymethyl-pyrrolidine-1-carboxylic acid tert-butyl ester 
• 121795-00-4 (2S,4R)-4-(benzyloxy)-1-(tert-butoxycarbonyl)pyrrolidine-2-carboxylic acid 
• 121794-97-6 O-benzyl-(2S,4R)-4-benzoyloxyprolinol 
• 121794-99-8 tert-butyl (2S,4R)-2-((benzyloxy)methyl)-4-hydroxypyrrolidine-1-carboxylate 
• 13726-69-7 (2S,4R)-4-hydroxy-1-[(2-methylpropan-2-yl)oxycarbonyl]pyrrolidine-2-carboxylic acid 
• 121794-96-5 N-((S)-1-Benzyloxymethyl-but-3-enyl)-benzamide 

Relevant articles and documents

Asymmetric Petasis Borono-Mannich Allylation Reactions Catalyzed by Chiral Biphenols

Chiral biphenols catalyze the asymmetric Petasis borono-Mannich allylation of aldehydes and amines through the use of a bench-stable allyldioxaborolane. The reaction proceeds via a two-step, one-pot process and requires 2–8 mole % of 3,3′-Ph2-BINOL as the optimal catalyst. Under microwave heating the reaction affords chiral homoallylic amines in excellent yields (up to 99 %) and high enantioselectivies (er up to 99:1). The catalytic reaction is a true multicomponent condensation reaction whereas both the aldehyde and the amine can possess a wide range of structural and electronic properties. Use of crotyldioxaborolane in the reaction results in stereodivergent products with anti- and syn-diastereomers both in good diastereoselectivities and enantioselectivities from the corresponding E- and Z-borolane stereoisomers.

Enantioselective transfer aminoallylation: Synthesis of optically active homoallylic primary amines

A camphorquinone-derived chiral homoallylic amine was found to react with various aldehydes via imine formation and asymmetric 2-azonia-Cope rearrangement to give optically active homoallylic primary amines. A practical level of enantioselectivity with hi