121824-02-0

Basic information

• Product Name: (2(R),S(R)) 3-chloro 1-p-tolylsulfinyl 2-propanol
• Synonyms: (2(R),S(R)) 3-chloro 1-p-tolylsulfinyl 2-propanol
• CAS NO: 121824-02-0
• Molecular Weight: 232.731
• Mol File: 121824-02-0.mol

Chemical Properties

• CAS DataBase Reference: (2(R),S(R)) 3-chloro 1-p-tolylsulfinyl 2-propanol(CAS DataBase Reference)
• NIST Chemistry Reference: (2(R),S(R)) 3-chloro 1-p-tolylsulfinyl 2-propanol(121824-02-0)
• EPA Substance Registry System: (2(R),S(R)) 3-chloro 1-p-tolylsulfinyl 2-propanol(121824-02-0)

Safety Data

• Hazardous Substances Data: 121824-02-0(Hazardous Substances Data)

Upstream product

• 1519-39-7 (R)-methyl p-tolyl sulfoxide 
• 104891-35-2 (R) 3-chloro 1-p-tolylsulfinyl 2-propanone 

Downstream Products

• 121824-04-2 (+)-<2(S),S(R)>-p-tolylsulfinyl-2-methyloxirane 
• 121824-06-4 (E)-(S)-1-((R)-Toluene-4-sulfinyl)-dec-4-en-2-ol 
• 121850-07-5 (Z)-(S)-1-((R)-Toluene-4-sulfinyl)-non-4-en-2-ol 
• 136580-80-8 <2(S),4(Z),S(R)> 1-p-tolylsulfinyl 4-decen-2-ol 
• 197848-99-0 (1R,2R,6S,7S)-2-((S)-Toluene-4-sulfinyl)-4-oxa-tricyclo[5.2.1.0^2,6]dec-8-en-3-one 
• 92210-76-9 (S_S)-3-[(4-methylphenyl)sulfinyl]furan-2(5H)-one 
• 92210-74-7 (E)-3-((R)-Toluene-4-sulfinyl)-prop-2-en-1-ol 

Relevant articles and documents

Dienophilic behavior of (S)-2-p-tolylsulfinyl butenolide

The study of the reactions of (S)-2-p-tolylsulfinyl butenolide (2) with cyclic and acyclic dienes is reported. The reactivity and stereoselectivity of this dienophile is compared with those of (S)-2-p-tolylsulfinyl cyclopentenone (3) in order to obtain information about the stereochemical models so far proposed.

Asymmetric Synthesis of the C-1-C-8 Fragment of Leukotriene B4 and C-11-C-20 Fragments of Leukotriene B4 and 12(S)-Hydroxy-5,8,14(Z), 10(E) Eicosatetraenoic Acid

An asymmetric synthesis of the C-1-C-8 fragment of LTB4 based on the reduction of optically active β-ketosulfoxides is described as well as the asymmetric synthesis of the C-11-C-20 fragments of LTB4 and 12(S)-hydroxy-5,8,14(Z), 10(E

OPTICALLY ACTIVE α-SULFINYL EPOXIDES: PRECURSORS OF CHIRAL FUNCTIONALIZED HOMOALLYLIC ALCOHOLS

An asymmetric synthesis of chiral functionalized homoallylic alcohols in both configurations is described from the corresponding optically active α-sulfinyl epoxides.