121824-99-5Relevant academic research and scientific papers
Allylsulfone in free radical reaction
Chuang,Hou,Wu
, p. 467 - 476 (2007/10/02)
A sulfonyl radical induced addition-cyclization reaction of vinylcyclopropane and 1,6-diene by using allylsulfone as sulfonyl radical precursor to give functionalized cyclopentane is described.
ADDITION RADICALAIRE D'HALOGENURES DE SULFONYLE. CYCLISATION ET BIFONCTIONNALISATION DU CYCLOOCTADIENE-1,5 ET DE DIENES-1,6
Riggi, I. De,Surzur, J.-M.,Bertrand, M. P.
, p. 7119 - 7126 (2007/10/02)
Radical addition of sulfonyl halides to non conjugated dienes, can lead to bifunctional carbocycles and heterocycles.Addition to 1,5-cyclooctadiene (1,5-COD and some diallylic derivates is reported.Scope and limits of the reaction are discussed.
