50487-72-4

Basic information

• Product Name: N,N-DIALLYL-4-METHYLBENZENESULFONAMIDE
• Synonyms: N,N-DIALLYL-4-METHYLBENZENESULFONAMIDE
• CAS NO: 50487-72-4
• Molecular Formula: C₁₃H₁₇NO₂S
• Molecular Weight: 251.34
• Mol File: 50487-72-4.mol
• Article Data: 32

Chemical Properties

• Boiling Point: 358.7°Cat760mmHg
• Flash Point: 170.7°C
• Appearance: /
• Density: 1.104g/cm³
• Vapor Pressure: 2.5E-05mmHg at 25°C
• Refractive Index: 1.54
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• PKA: -6.18±0.70(Predicted)
• CAS DataBase Reference: N,N-DIALLYL-4-METHYLBENZENESULFONAMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-DIALLYL-4-METHYLBENZENESULFONAMIDE(50487-72-4)
• EPA Substance Registry System: N,N-DIALLYL-4-METHYLBENZENESULFONAMIDE(50487-72-4)

Safety Data

• Hazardous Substances Data: 50487-72-4(Hazardous Substances Data)

Usage

General Description

N,N-Diallyl-4-methylbenzenesulfonamide is a chemical compound that is commonly used as a monomer in the manufacture of polymers and resins. It is a sulfonamide derivative with two allyl groups attached to the nitrogen atom and a methyl group attached to the benzene ring. N,N-DIALLYL-4-METHYLBENZENESULFONAMIDE is used in the production of cross-linked polymers, particularly in thermosetting resins and materials, due to its ability to undergo polymerization to form a network structure. N,N-Diallyl-4-methylbenzenesulfonamide is also used as a cross-linking agent in the formulation of adhesives, coatings, and composites, providing enhanced mechanical and thermal properties to the final products. Additionally, it is known for its high heat resistance and chemical stability, making it a valuable ingredient in various industrial and commercial applications.

InChI:InChI=1/C13H17NO2S/c1-4-10-14(11-5-2)17(15,16)13-8-6-12(3)7-9-13/h4-9H,1-2,10-11H2,3H3

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 
• 124-02-7 diallylamine 
• 557-40-4 Allyl ether 
• 70-55-3 toluene-4-sulfonamide 
• 92954-34-2 O-allyl-N,N'-dicyclohexyl isourea 
• 1469-70-1 allyl ethyl carbonate 
• 106-95-6 allyl bromide 
• 133886-40-5 N-tosyl-N-allylpropargylamine 
• 50487-71-3 4-methyl-N-(2-propenyl)benzenesulfonamide 
• 107-05-1 3-chloroprop-1-ene 
• 771477-49-7 (E)-3-benbenzylidene-5-phenylpent-4-yn-2-one 
• 1174640-63-1 isopropyl N-( p-toluenesulfonyl)propionimidate 
• 107-18-6 allyl alcohol 
• 852051-00-4 1-(toluene-4-sulfonyl)-2,3-dehydro-4-piperidone 

Downstream Products

• 16851-72-2 1-[(4-methylphenyl)sulfonyl]-2,5-dihydro-1H-pyrrole 
• 212326-97-1 3-methyl-4-methylene-2-(4-tolylsulfonyl)pyrrolidine 
• 124982-64-5 2,6-Dichloromethyl-4-p-tolylsulfonylperhydro-1,4-selenazine 
• 124982-63-4 2,6-Dibromomethyl-4-p-tolylsulfonylperhydro-1,4-selenazine 
• 455-31-2 difluoromethylbenzene 
• 130719-30-1 1-(toluene-4-sulfonyl)-2,3-dihydro-1H-pyrrole 
• 74-85-1 ethene 
• 165883-19-2 (+)-(R)-3-phenyl-N-(p-toluenesulfonyl)pyrrolidine 

Relevant articles and documents

Immobilisation of an ionically tagged Hoveyda catalyst on a supported ionic liquid membrane: An innovative approach for metathesis reactions in a catalytic membrane reactor

This study aimed at developing an innovative strategy to recycle homogeneous olefin metathesis catalysts by the combination of complementary green processes, namely organic solvent nanofiltration coupled with ionic liquid advantages. The immobilisation of

One-pot chemoenzymatic reactions in water enabled by micellar encapsulation

The use of micellar conditions to enable one-pot reactions involving both transition metal and enzymatic catalysts is reported. Representative enzymatic transformations under micellar conditions are unaffected by the presence of non-ionic surfactants, including designer surfactants such as TPGS-750-M. Furthermore, the presence of enzymes has a negligible effect on transition metal catalysis under micellar conditions in water. Finally, three one-pot chemoenzymatic reactions in water are reported in which the micelle-forming surfactant TPGS-750-M is a crucial factor for reaction efficiency.

Aminoxyl-Catalyzed Electrochemical Diazidation of Alkenes Mediated by a Metastable Charge-Transfer Complex

We report the development of a new aminoxyl radical catalyst, CHAMPO, for the electrochemical diazidation of alkenes. Mediated by an anodically generated charge-transfer complex in the form of CHAMPO-N3, radical diazidation was achieved across a broad scope of alkenes without the need for a transition metal catalyst or a chemical oxidant. Mechanistic data support a dual catalytic role for the aminoxyl serving as both a single-electron oxidant and a radical group transfer agent.