50487-72-4

Usage

Uses

Used in Polymer and Resin Production:
N,N-DIALLYL-4-METHYLBENZENESULFONAMIDE is used as a monomer for the synthesis of cross-linked polymers, particularly in thermosetting resins and materials. Its ability to undergo polymerization contributes to the formation of a network structure, which is essential for the creation of durable and stable products.
Used in Adhesive Formulation:
In the adhesive industry, N,N-DIALLYL-4-METHYLBENZENESULFONAMIDE is used as a cross-linking agent. Its inclusion in adhesive formulations enhances the mechanical and thermal properties of the final products, leading to improved adhesion and durability.
Used in Coating Development:
N,N-DIALLYL-4-METHYLBENZENESULFONAMIDE is also utilized in the development of coatings, where it acts as a cross-linking agent. This role improves the mechanical strength, thermal stability, and overall performance of the coatings, making them suitable for various applications, including automotive, aerospace, and construction.
Used in Composite Manufacturing:
N,N-DIALLYL-4-METHYLBENZENESULFONAMIDE is employed in the manufacturing of composites to provide enhanced mechanical properties and thermal resistance. Its use in composite materials contributes to the creation of lightweight, strong, and heat-resistant products that are ideal for various industrial applications.
Overall, N,N-DIALLYL-4-METHYLBENZENESULFONAMIDE is a versatile chemical compound with applications in various industries, including polymer and resin production, adhesive formulation, coating development, and composite manufacturing, due to its ability to improve the mechanical and thermal properties of the final products.

InChI:InChI=1/C13H17NO2S/c1-4-10-14(11-5-2)17(15,16)13-8-6-12(3)7-9-13/h4-9H,1-2,10-11H2,3H3

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 
• 124-02-7 diallylamine 
• 557-40-4 Allyl ether 
• 70-55-3 toluene-4-sulfonamide 
• 92954-34-2 O-allyl-N,N'-dicyclohexyl isourea 
• 1469-70-1 allyl ethyl carbonate 
• 106-95-6 allyl bromide 
• 133886-40-5 N-tosyl-N-allylpropargylamine 
• 50487-71-3 4-methyl-N-(2-propenyl)benzenesulfonamide 
• 107-05-1 3-chloroprop-1-ene 
• 771477-49-7 (E)-3-benbenzylidene-5-phenylpent-4-yn-2-one 
• 1174640-63-1 isopropyl N-( p-toluenesulfonyl)propionimidate 
• 107-18-6 allyl alcohol 
• 852051-00-4 1-(toluene-4-sulfonyl)-2,3-dehydro-4-piperidone 

Downstream Products

• 139566-32-8 (3R,4R)-3-Dimethoxymethyl-4-methyl-1-(toluene-4-sulfonyl)-pyrrolidine 
• 139566-32-8 (3R,4S)-3-Dimethoxymethyl-4-methyl-1-(toluene-4-sulfonyl)-pyrrolidine 
• 124982-65-6 1-p-Tolylsulfonyl-4-phenyl-3,5-dibromomethylperhydro-1,4-azaselenonium bromide 
• 121824-99-5 chloromethyl-3 tosylmethyl-4 N-tosyl pyrrolidine 
• 121824-99-5 chloromethyl-3 tosylmethyl-4 N-tosyl pyrrolidine 
• 121825-00-1 bromomethyl-3 tosylmethyl-4 N-tosyl pyrrolidine 
• 121825-00-1 bromomethyl-3 tosylmethyl-4 N-tosyl pyrrolidine 
• 124982-66-7 1-p-Tolylsulfonyl-4-phenyl-3,5-dichloromethylperhydro-1,4-azaselenonium chloride 
• 124982-64-5 2,6-Dichloromethyl-4-p-tolylsulfonylperhydro-1,4-selenazine 
• 124982-59-8 1,1-Dichloro-2,6-dichloromethyl-4-p-tolylsulfonylperhydro-1,4-selenazine 
• 124982-63-4 2,6-Dibromomethyl-4-p-tolylsulfonylperhydro-1,4-selenazine 
• 124982-58-7 1,1-Dibromo-2,6-dibromomethyl-4-p-tolylsulfonylperhydro-1,4-selenazine 
• 124982-61-2 1,1-Dibromo-2,6-dibromomethyl-4-p-tolylsulfonylperhydro-1,4-tellurazine 
• 16851-72-2 1-[(4-methylphenyl)sulfonyl]-2,5-dihydro-1H-pyrrole 

Relevant academic research and scientific papers

Immobilisation of an ionically tagged Hoveyda catalyst on a supported ionic liquid membrane: An innovative approach for metathesis reactions in a catalytic membrane reactor

This study aimed at developing an innovative strategy to recycle homogeneous olefin metathesis catalysts by the combination of complementary green processes, namely organic solvent nanofiltration coupled with ionic liquid advantages. The immobilisation of

Water-soluble complexes of an acrylamide copolymer and ionic liquids for inhibiting shale hydration

Here, we report water-soluble complexes of an acrylamide copolymer and ionic liquids for inhibiting shale hydration. The copolymer, denoted as PAAT, was synthesised via copolymerisation of acrylamide (AM), acrylic acid (AA) and N,N-diallyl-4-methylbenzene

One-pot chemoenzymatic reactions in water enabled by micellar encapsulation

The use of micellar conditions to enable one-pot reactions involving both transition metal and enzymatic catalysts is reported. Representative enzymatic transformations under micellar conditions are unaffected by the presence of non-ionic surfactants, including designer surfactants such as TPGS-750-M. Furthermore, the presence of enzymes has a negligible effect on transition metal catalysis under micellar conditions in water. Finally, three one-pot chemoenzymatic reactions in water are reported in which the micelle-forming surfactant TPGS-750-M is a crucial factor for reaction efficiency.

Synthesis of N -Sulfonyl- and N -Acylpyrroles via a Ring-Closing Metathesis/Dehydrogenation Tandem Reaction

N -Sulfonyl- and N -acylpyrroles were synthesized via olefin ring-closing metathesis of diallylamines and in situ oxidative aromatization in the presence of the ruthenium Grubbs catalyst and a suitable copper catalyst. In the presence of Cu(OTf) 2/s

Aminoxyl-Catalyzed Electrochemical Diazidation of Alkenes Mediated by a Metastable Charge-Transfer Complex

We report the development of a new aminoxyl radical catalyst, CHAMPO, for the electrochemical diazidation of alkenes. Mediated by an anodically generated charge-transfer complex in the form of CHAMPO-N3, radical diazidation was achieved across a broad scope of alkenes without the need for a transition metal catalyst or a chemical oxidant. Mechanistic data support a dual catalytic role for the aminoxyl serving as both a single-electron oxidant and a radical group transfer agent.

Nickel(0)-Catalyzed N-Allylation of Amides and p-Toluenesulfonamide with Allylic Alcohols under Neat and Neutral Conditions

Nickel(0)-catalyzed direct N-allylation of amides and p-toluenesulfonamide with allylic alcohols took place in the presence of Ni0–diphosphine complexes. The corresponding N-allylated (and/or N,N-diallylated) products were obtained in moderate to high yields under neutral conditions.

Origins of initiation rate differences in ruthenium olefin metathesis catalysts containing chelating benzylidenes

A series of second-generation ruthenium olefin metathesis catalysts was investigated using a combination of reaction kinetics, X-ray crystallography, NMR spectroscopy, and DFT calculations in order to determine the relationship between the structure of the chelating o-alkoxybenzylidene and the observed initiation rate. Included in this series were previously reported catalysts containing a variety of benzylidene modifications as well as four new catalysts containing cyclopropoxy, neopentyloxy, 1-adamantyloxy, and 2-adamantyloxy groups. The initiation rates of this series of catalysts were determined using a UV/vis assay. All four new catalysts were observed to be faster-initiating than the corresponding isopropoxy control, and the 2-adamantyloxy catalyst was found to be among the fastest-initiating Hoveyda-type catalysts reported to date. Analysis of the X-ray crystal structures and computed energy-minimized structures of these catalysts revealed no correlation between the Ru-O bond length and Ru-O bond strength. On the other hand, the initiation rate was found to correlate strongly with the computed Ru-O bond strength. This latter finding enables both the rationalization and prediction of catalyst initiation through the calculation of a single thermodynamic parameter in which no assumptions about the mechanism of the initiation step are made.

A medium fluorous Grubbs-Hoveyda 2nd generation catalyst for phase transfer catalysis of ring closing metathesis reactions

A fluorous Grubbs-Hoveyda metathesis catalyst supported on Teflon powder, that readily moves between the solid phase (Teflon) and the liquid phase (DMF) was prepared. By modulating the hydrophobicity of the reaction medium at the end of the reaction, the supported catalyst could be recovered by simple filtration even though the catalyst existed in a homogeneous state during the reaction. In RCM reactions, the catalyst could be reused up to three times with only a slight loss in reactivity with each subsequent cycle.

Iodine-catalyzed expeditious synthesis of sulfonamides from sulfonyl hydrazides and amines

A new synthesis of sulfonamides has been developed via an iodine-catalyzed sulfonylation of amines with arylsulfonyl hydrazides. This metal-free strategy employs readily accessible and easy to handle starting materials, catalysts and oxidants, and can be easily conducted under mild conditions, providing a convenient access to a wide range of sulfonamides in moderate to excellent yields within a short reaction time.

Ligand Control of E/Z Selectivity in Nickel-Catalyzed Transfer Hydrogenative Alkyne Semireduction

A nickel-catalyzed transfer hydrogenative alkyne semireduction protocol that can be applied to both internal and terminal alkynes using formic acid and Zn as the terminal reductants has been developed. In the case of internal alkynes, the (E)- or (Z)-olefin isomer can be accessed selectively under the same reaction conditions by judicious inclusion of a triphos ligand.