121895-79-2

Upstream product

• 121960-61-0 (S)-3-(4-Methoxy-phenyl)-5-trimethylsilanyl-cyclohex-2-enone 
• 116498-73-8 (R)-(+)-3-tolylthio-5-trimethylsilyl-2-cyclohexenone 
• 116502-11-5 (3R,5R)-3-(4'-methylbenzenethio)-5-(trimethylsilyl)cyclohexanone 

Downstream Products

• 121960-60-9 2-[(R)-1-(4-Methoxy-phenyl)-4-oxo-cyclohex-2-enyl]-N,N-dimethyl-acetamide 
• 77844-21-4 (R)-(-)-O-methyljoubertiamine 
• 121895-78-1 2-[(1S,5R)-1-(4-Methoxy-phenyl)-5-trimethylsilanyl-cyclohex-2-enyl]-N,N-dimethyl-acetamide 

Relevant academic research and scientific papers

Enantioselective preparation of 1,3-cyclohexadiene and 1,4-cycloheptadiene derivatives: Synthesis of (+)-dictyopterene C'

Starting from optically active 5-trimethylsilyl-2-cyclohexen-1-one derivatives, the title dienes were synthesized by using silicon-mediated 1,4-elimination as a key step. A straightforward synthesis of the unnatural enantiomer of (-)-dictyopterene C' util

Synthesis of (R)-(-)-O-Methyljoubertiamine

The title compound was synthesized by utilizing sigmatropic rearrangement of 3-substituted 2-cyclohexenol derivative for the construction of optically active quaternary carbon center.