1218989-10-6Relevant articles and documents
A catalyst-free benzylic C-H bond olefination of azaarenes for direct mannich-like reactions
Yan, Yizhe,Xu, Kun,Fang, Yang,Wang, Zhiyong
, p. 6849 - 6855 (2011/10/04)
A highly efficient synthesis of trans-alkenylazaarene under catalyst-free conditions was developed via the addition of methylazaarenes to N-sulfonyl aldimines and a subsequent C-N elimination in situ. A one-pot procedure for this addition-elimination was also developed. The reaction could tolerate a broad substrate scope and give the corresponding alkenylazaarenes in high yields.