1218993-28-2Relevant academic research and scientific papers
Hydroxyl group orientation affects hydrolysis rates of methyl α-septanosides
Markad, Shankar D.,Miller, Shawn M.,Morton, Martha,Peczuh, Mark W.
scheme or table, p. 1209 - 1212 (2010/04/05)
Hydrolysis rates for three related methyl α-septanosides were obtained. The septanosides were synthesized via mCPBA epoxidation and methanolysis of d-mannose, d-galactose, and d-glucose-based oxepines. The rate of hydrolysis correlates with the orientation of hydroxyl groups on the septanose ring in a manner analogous to pyranosides.
