121926-03-2Relevant academic research and scientific papers
Cyclization of η3-benzylpalladium intermediates derived from carbene insertion
Gutman, Eugene S.,Arredondo, Vanessa,Van Vranken, David L.
, p. 5498 - 5501 (2015/01/09)
Migratory insertion of benzylidene carbene ligands into arylpalladium(II) species generates η3-benzylpalladium intermediates that can cyclize to generate five- and six-membered rings with new sp3 centers. The reaction tolerates a ran
Etude de l'annelation a partir de derives dibromomes-1,4 et -1,5 en presence de carbanions
Canonne, P.,Plamondon, J.
, p. 555 - 564 (2007/10/02)
Primary-secondary dibromides have been prepared from the corresponding diols and used with carbon acids to prepare 1,2-disubstituted cyclic compounds.With unsymmetrical carbon acid in presence of NaH in DME, a high diastereoselection of the trans isomer i
