1219844-16-2Relevant academic research and scientific papers
Copper-catalyzed amination of primary benzylic C?H bonds with primary and secondary sulfonamides
Powell, David A.,Fan, Hope
supporting information; experimental part, p. 2726 - 2729 (2010/08/03)
A room-temperature, copper-catalyzed amination of primary benzylic C?H bonds with primary and secondary sulfonamides is described. The reaction is applicable to the coupling of a range of primary and secondary benzylic hydrocarbons with a diverse set of sulfonamides and is tolerant of substitution on both coupling partners. Factors which influence the selectivity of C?H functionalization between primary and secondary sites are examined.
