1220193-95-2Relevant academic research and scientific papers
Iminium-allenamine cascade catalysis: One-pot access to chiral 4Hchromenes by a highly enantioselective michael-michael sequence
Zhang, Xinshuai,Zhang, Shilei,Wang, Wei
supporting information; experimental part, p. 1481 - 1484 (2010/05/18)
Chemical Equation Presented Taking the Michael-Michael: A cascade Michael-Michael reaction of aryl or alkyl alkynals, involving an unprecedented iminium - allenamine sequence, is efficiently catalyzed by a chiral diphenylprolinol TBDMS ether, and affords highly functionalized 4H-chromenes in high yields. TBDMS = tert-butyldimethylsilyl.
