122039-99-0

Basic information

• Product Name: methyl (15R)-16-hydroxy-8,11,13-abietatrien-18-oate
• Synonyms: methyl (15R)-16-hydroxy-8,11,13-abietatrien-18-oate
• CAS NO: 122039-99-0
• Molecular Weight: 330.467
• Mol File: 122039-99-0.mol

Chemical Properties

• CAS DataBase Reference: methyl (15R)-16-hydroxy-8,11,13-abietatrien-18-oate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (15R)-16-hydroxy-8,11,13-abietatrien-18-oate(122039-99-0)
• EPA Substance Registry System: methyl (15R)-16-hydroxy-8,11,13-abietatrien-18-oate(122039-99-0)

Safety Data

• Hazardous Substances Data: 122039-99-0(Hazardous Substances Data)

Upstream product

• 22465-60-7 methyl abieta-8,11,13,15-tetraen-18-oate 

Downstream Products

• 122040-06-6 methyl (15R)-16-benzoyloxy-12-(1-phenyl-1H-tetrazol-5-yloxy)-8,11,13-abietatrien-18-oate 
• 122039-94-5 methyl (15S)-16-benzoyloxy-12-(1-phenyl-1H-tetrazol-5-yloxy)-8,11,13-abietatrien-18-oate 
• 122040-07-7 methyl (15R)-16-hydroxy-12-(1-phenyl-1H-tetrazol-5-yloxy)-8,11,13-abietatrien-18-oate 
• 122039-95-6 methyl (15S)-16-hydroxy-12-(1-phenyl-1H-tetrazol-5-yloxy)-8,11,13-abietatrien-18-oate 
• 122040-02-2 methyl (15R)-12-acetoxy-16-benzoyloxy-8,11,13-abietatrien-18-oate 
• 122039-86-5 methyl (15S)-12-acetoxy-16-benzoyloxy-8,11,13-abietatrien-18-oate 
• 122090-00-0 (15R)-12,16-methylenedioxy-18-tosyloxy-8,11,13-abietatriene 
• 122039-91-2 (15S)-12,16-methylenedioxy-18-tosyloxy-8,11,13-abietatriene 
• 122040-01-1 methyl (15R)-12-acetyl-16-benzoyloxy-8,11,13-abietatrien-18-oate 
• 122039-85-4 methyl (15S)-12-acetyl-16-benzoyloxy-8,11,13-abietatrien-18-oate 
• 122040-05-5 methyl (16R)-16-benzoyloxy-12-hydroxy-8,11,13-abietatrien-18-oate 
• 122039-93-4 methyl (16S)-16-benzoyloxy-12-hydroxy-8,11,13-abietatrien-18-oate 
• 122039-97-8 methyl (15S)-16-(4-nitrobenzoyloxy)-8,11,13-abietatrien-18 oate 
• 122040-00-0 methyl (15R)-16-benzoyloxy-8,11,13-abietatrien-18-oate 

Relevant articles and documents

The Synthesis of Methyl (15S)-16-Hydroxydehydroabietate and Its (15R)-Epimer

In order to elucidate the absolute configuration of C-15 in natural 16-hydroxydehyroabietic acid, a metabolite of (+)-dehydroabietic acid in rabbits, methyl (+)-dehydroabietate was transformed into methyl (15S)-16-hydroxy-8,11,13-abietatrien-18-oate (3a) and its (15R)-epimer (3b).The synthetic 3a was identical with a methyl ester derived from the natural acid.Thus, the absolute configuration of C-15 in natural 16-hydroxydehydroabietic acid was conclusively assigned as an S-configuration.