122086-32-2Relevant academic research and scientific papers
Cerium(IV) oxidations, X: Oxidation of ω-phenylalkyldicarbonyl- and dicarbonyl-analogous derivatives
Holzgrabe,Reinhardt,Zlotos
, p. 515 - 523 (2007/10/02)
Oxidations of the ω-phenylalkylmalonate derivatives 1a-f afford cyclization products 2 as well as nitro-, alcohol and acetoxy compounds 3-7. The distribution of products depends sensitively on the temp. and on the water content of the reaction medium and
OXIDATIVE DEPROTONATION OF CARBONYL COMPOUNDS BY Fe(III) SALTS
Citterio, Attilio,Cerati, Anna,Sebastiano, Roberto,Finzi, Claudia,Santi, Roberto
, p. 1289 - 1292 (2007/10/02)
Iron (III) salts (perchlorate and nitrate nonahydrate) in acetonitrile or acetic anhydride at 0-50 deg C oxidize the α-position of malonic esters efficiently via the corresponding radicals.In the presence of olefins and aromatics, inter- and intramolecular free radical chain or oxidative additions are observed.
