1221184-57-1

Basic information

• Product Name: 4'-acetyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)biphenyl
• Synonyms: 4'-acetyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)biphenyl
• CAS NO: 1221184-57-1
• Molecular Weight: 322.212
• Mol File: 1221184-57-1.mol

Chemical Properties

• CAS DataBase Reference: 4'-acetyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)biphenyl(CAS DataBase Reference)
• NIST Chemistry Reference: 4'-acetyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)biphenyl(1221184-57-1)
• EPA Substance Registry System: 4'-acetyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)biphenyl(1221184-57-1)

Safety Data

• Hazardous Substances Data: 1221184-57-1(Hazardous Substances Data)

Upstream product

• 269410-07-3 1,2-bis(4,4,5,5-tetramethyl-[1,3,2]dioxabororan-2-yl)benzene 
• 13329-40-3 4-Iodoacetophenone 
• 171364-81-1 1-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)ethanone 

Relevant articles and documents

A modular synthesis of functionalised phenols enabled by controlled boron speciation

A modular synthesis of functionalised biaryl phenols from two boronic acid derivatives has been developed via one-pot Suzuki-Miyaura cross-coupling, chemoselective control of boron solution speciation to generate a reactive boronic ester in situ, and oxidation. The utility of this method has been further demonstrated by application in the synthesis of drug molecules and components of organic electronics, as well as within iterative cross-coupling.

Platinum-catalysed diborylation of arynes: Synthesis and reaction of 1,2-diborylarenes

Arynes are found to be facilely inserted into bis(pinacolato)diboron by using a platinum-isocyanide catalyst, affording diverse 1,2-diborylarenes, which can be converted into o-terphenyls via Suzuki-Miyaura coupling reaction.