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4'-Iodoacetophenone
Cas No: 13329-40-3
No Data 1 Gram Metric Ton/Day Nanjing Fred Technology Co.,Ltd. Contact Supplier
High quality 4'-Iodoacetophenone supplier in China
Cas No: 13329-40-3
No Data 1 Kilogram 30 Metric Ton/Month Simagchem Corporation Contact Supplier
4'-Iodoacetophenone manufacturer with low price
Cas No: 13329-40-3
No Data 1 Gram 1000 Metric Ton/Month Hangzhou JINLAN Pharm-Drugs Technology Co., Ltd Contact Supplier
4'-Iodoacetophenone
Cas No: 13329-40-3
No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
4'-Iodoacetophenone
Cas No: 13329-40-3
No Data 1 Kilogram 20 Metric Ton/Month Henan Allgreen Chemical Co.,Ltd Contact Supplier
4'-Iodoacetophenone
Cas No: 13329-40-3
No Data No Data No Data Chemwill Asia Co., Ltd. Contact Supplier
4'-Iodoacetophenone
Cas No: 13329-40-3
USD $ 4.0-4.0 / Kilogram 1 Kilogram 1-10 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
4'-Iodoacetophenone
Cas No: 13329-40-3
USD $ 1.0-1.0 / Kilogram 1 Kilogram 1000 Metric Ton/Year Henan Sinotech Import&Export Corporation Contact Supplier
13329-40-3
Cas No: 13329-40-3
No Data 1 Kilogram 500 Metric Ton/Year Henan Tianfu Chemical Co., Ltd. Contact Supplier
High purity 1-(4-iodophenyl)ethan-1-one
Cas No: 13329-40-3
No Data 10 Gram 200 Kilogram/Day Hubei Jusheng Technology Co., Ltd., Contact Supplier

13329-40-3 Usage

Chemical Properties

Pale brown to brown crystalline powder
InChI:InChI=1/C8H7IO/c1-6(10)7-2-4-8(9)5-3-7/h2-5H,1H3

13329-40-3 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Alfa Aesar (A16794)  4'-Iodoacetophenone, 98%    13329-40-3 100g 1980.0CNY Detail
Alfa Aesar (A16794)  4'-Iodoacetophenone, 98%    13329-40-3 25g 621.0CNY Detail
Alfa Aesar (A16794)  4'-Iodoacetophenone, 98%    13329-40-3 5g 170.0CNY Detail

13329-40-3Synthetic route

1-(4-iodophenyl)ethanol
68120-56-9, 104013-25-4, 53207-29-7

1-(4-iodophenyl)ethanol

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

Conditions
ConditionsYield
With silica-supported Jones reagent In dichloromethane for 0.00269444h;99.6%
With 1,10-Phenanthroline; iron(III)-acetylacetonate; potassium carbonate In toluene for 48h; Reflux; Green chemistry;94%
With [bis({2‐[bis(propan‐2‐yl)phosphanyl]ethyl})amine](borohydride)(carbonyl)(hydride)iron(II) In toluene at 120℃; for 12h; Glovebox; Schlenk technique; Inert atmosphere;94%
1-ethynyl-4-iodobenzene
766-99-4

1-ethynyl-4-iodobenzene

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

Conditions
ConditionsYield
With tetrakis(p-sulfonatophenyl)porphyrin cobalt(III) trisodium salt hexahydrate; water; bis(trifluoromethanesulfonyl)amide In methanol at 80℃; for 12h; Sealed tube;97%
4-Aminoacetophenone
99-92-3

4-Aminoacetophenone

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

Conditions
ConditionsYield
Stage #1: p-aminobenzophenone With hydrogenchloride In water at 0 - 5℃; for 0.166667h;
Stage #2: With 1-methyl-3-(2-[2-(1-methyl-1H-imidazol-3-ium-3-yl)ethyloxy]ethyl)-1H-imidazol-3-ium dinitrite In water for 0.166667h;
Stage #3: With potassium iodide In water at 20℃; for 0.166667h; Ionic liquid;
95%
With toluene-4-sulfonic acid; sodium iodide In water; acetonitrile at 10 - 20℃; for 2h; Inert atmosphere;94%
With N-iodo-succinimide; sodium nitrite In N,N-dimethyl-formamide at 20℃; for 4h; Reagent/catalyst; Temperature; Solvent;92%
1-(p-acetophenyl)-3,3-diethyl-1-triazene
86452-55-3

1-(p-acetophenyl)-3,3-diethyl-1-triazene

A

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

B

benzene
71-43-2

benzene

Conditions
ConditionsYield
With sulfonic acid resin (H+ form, Bio-Rad AG 50W-12); sodium iodide In acetonitrile at 75℃; for 0.133333h;A 95%
B n/a
1-(3,4-Diiodocyclohexa-1,3-dienyl)ethanone
85972-28-7

1-(3,4-Diiodocyclohexa-1,3-dienyl)ethanone

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene95%
1,2,2-triphenyl-1-iodoethylene
22021-09-6

1,2,2-triphenyl-1-iodoethylene

4,5-dimethoxy-2-(trimethylsilyl)phenyl trifluoromethanesulfonate

4,5-dimethoxy-2-(trimethylsilyl)phenyl trifluoromethanesulfonate

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

Conditions
ConditionsYield
With thallium(I) acetate; cesium fluoride; bis(dibenzylideneacetone)-palladium(0) In toluene; acetonitrile at 90℃; for 8h;95%
4-acetophenyl triflate
109613-00-5

4-acetophenyl triflate

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

Conditions
ConditionsYield
With [Cp*Ru(CH3CN)3]OTf; sodium iodide at 120℃; for 12h; Inert atmosphere;95%
With iodine; lithium fluoride; sodium iodide In acetonitrile at 25℃; for 24h; Inert atmosphere; UV-irradiation; Schlenk technique;20%
Multi-step reaction with 2 steps
1: KOAc / PdCl2(dppf) / dimethylsulfoxide / 3 h / 80 °C
2: 30 percent / aq. NaI; chloramine-T / tetrahydrofuran / 6 h
View Scheme
1-(p-acetophenyl)-3,3-diethyl-1-triazene
86452-55-3

1-(p-acetophenyl)-3,3-diethyl-1-triazene

A

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

B

acetophenone
98-86-2

acetophenone

Conditions
ConditionsYield
With cation exchange resin BioRad AG 50W-X12 (H+); sodium iodide In acetonitrile at 75℃; Product distribution; further solvent: THF, DMSO;A 94%
B 6%
para-bromoacetophenone
99-90-1

para-bromoacetophenone

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

Conditions
ConditionsYield
With copper(I) oxide; L-proline; potassium iodide In ethanol at 110℃; for 30h; Schlenk technique; Inert atmosphere; Sealed tube;92%
With tributylphosphine; potassium iodide; nickel dibromide In N,N,N,N,N,N-hexamethylphosphoric triamide; N,N-dimethyl-formamide at 50℃; for 1.5h;66%
With N,N,N,N,N,N-hexamethylphosphoric triamide; copper(l) iodide; potassium iodide at 150 - 160℃; for 5h;60%
1-(p-acetophenyl)-3,3-diethyl-1-triazene
86452-55-3

1-(p-acetophenyl)-3,3-diethyl-1-triazene

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

Conditions
ConditionsYield
With chloro-trimethyl-silane; sodium iodide In acetonitrile at 60℃; for 0.0833333h;92%
4-acetylphenylboronic acid
149104-90-5

4-acetylphenylboronic acid

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

Conditions
ConditionsYield
With iodine; potassium carbonate In acetonitrile at 80℃; for 8h; Inert atmosphere; Schlenk technique; Sealed tube;91%
With sodium nitrite In acetonitrile at 80℃; for 5h; Sealed tube;86%
With 1,10-Phenanthroline; oxygen; potassium iodide; copper(ll) bromide In N,N-dimethyl-formamide at 80℃; for 20h;76%
1-(4-acetylphenyl)diazonium tetrafluoroborate
350-47-0

1-(4-acetylphenyl)diazonium tetrafluoroborate

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

Conditions
ConditionsYield
With N-iodo-succinimide; sodium nitrite In dimethyl sulfoxide at 20℃; for 2.5h;90%
With diiodomethane; tetrabutylammonium perchlorate In methanol; N,N-dimethyl-formamide at 20℃; for 3h; Sandmeyer Reaction; Electrochemical reaction;87%
iodobenzene
591-50-4

iodobenzene

4-(phenylethynyl)nitrobenzene
1942-30-9

4-(phenylethynyl)nitrobenzene

2-(trimethylsilyl)phenyl trifluoromethanesulfonate
88284-48-4

2-(trimethylsilyl)phenyl trifluoromethanesulfonate

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

Conditions
ConditionsYield
With thallium(I) acetate; cesium fluoride; bis(dibenzylideneacetone)-palladium(0) In toluene; acetonitrile at 90℃; for 8h;89%
1-iodo-4-(prop-1-en-2-yl)benzene
561023-21-0

1-iodo-4-(prop-1-en-2-yl)benzene

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

Conditions
ConditionsYield
With sodium tetrafluoroborate; [Cu(salicylate)2(NCMe)]2; tetrabutyl-ammonium chloride; oxygen In tetrahydrofuran at 60℃; for 12h;85%
carbon monoxide
201230-82-2

carbon monoxide

para-diiodobenzene
624-38-4

para-diiodobenzene

methylmercury(II) iodide
143-36-2

methylmercury(II) iodide

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

Conditions
ConditionsYield
With dichloro bis(acetonitrile) palladium(II); tetra-(n-butyl)ammonium iodide In N,N,N,N,N,N-hexamethylphosphoric triamide under 760 Torr; for 5.5h; Ambient temperature;83%
4-Aminoacetophenone
99-92-3

4-Aminoacetophenone

bis(trifluoromethanesulfonyl)amide
82113-65-3

bis(trifluoromethanesulfonyl)amide

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

Conditions
ConditionsYield
Stage #1: bis(trifluoromethanesulfonyl)amide With tert.-butylnitrite; acetic acid In ethanol Cooling with ice;
Stage #2: p-aminobenzophenone With tetraethylammonium iodide In water at 20℃;
81%
carbon monoxide
201230-82-2

carbon monoxide

tetramethylstannane
594-27-4

tetramethylstannane

4-iodobenzenediazonium tetrafluoroborate
1514-50-7

4-iodobenzenediazonium tetrafluoroborate

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

Conditions
ConditionsYield
palladium diacetate In acetonitrile under 6619.6 Torr; for 1.5h; Heating;79%
With palladium diacetate In acetonitrile for 0.5h; Ambient temperature;79%
4-(2-methyl-[1,3]dioxolan-2-yl)-phenylamine
19073-16-6

4-(2-methyl-[1,3]dioxolan-2-yl)-phenylamine

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

Conditions
ConditionsYield
With N-iodo-succinimide; sodium nitrite In N,N-dimethyl-formamide at 20℃; for 4h;75%
Multi-step reaction with 2 steps
1: sodium nitrite; N-iodo-succinimide / N,N-dimethyl-formamide / 4 h / 20 °C
2: sodium nitrite; N-iodo-succinimide / N,N-dimethyl-formamide / 4 h / 20 °C
View Scheme
Multi-step reaction with 3 steps
1: sodium nitrite; N-iodo-succinimide / N,N-dimethyl-formamide / 4 h / 20 °C
2: tert.-butylnitrite / water; ethanol / 2 h / 0 - 20 °C
3: sodium nitrite; N-iodo-succinimide / dimethyl sulfoxide / 2.5 h / 20 °C
View Scheme
4-ethyl-1-iodobenzene
25309-64-2

4-ethyl-1-iodobenzene

A

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

B

1-(4-iodophenyl)ethanol
68120-56-9, 104013-25-4, 53207-29-7

1-(4-iodophenyl)ethanol

Conditions
ConditionsYield
With 1-hydroxy-1,2-benzodioxol-3-(1H)-one; tris(2,2'-bipyridyl)ruthenium dichloride; water at 30℃; for 10h; Reagent/catalyst; Irradiation; Inert atmosphere;A 8%
B 71%
2-(4-iodophenyl)propan-2-ol
60514-82-1

2-(4-iodophenyl)propan-2-ol

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

Conditions
ConditionsYield
With bismuth(lll) trifluoromethanesulfonate; dipotassium peroxodisulfate; silver nitrate In water at 30℃; for 24h; Inert atmosphere; Green chemistry;71%
4-ethyl-1-iodobenzene
25309-64-2

4-ethyl-1-iodobenzene

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

Conditions
ConditionsYield
With tert.-butylhydroperoxide; C26H23ClN8ORu In water at 20℃; for 2h; Catalytic behavior; Schlenk technique;66%
With tert.-butylhydroperoxide at 90℃; for 5h; Neat (no solvent);
With calcined praseodymium incorporated AlPO-5 molecular sieves ((Al+P)/Pr = 25); air In neat liquid at 120℃; for 6h; Green chemistry;
With oxygen; Langlois reagent In acetonitrile at 25℃; under 760.051 Torr; for 12h; Irradiation; Green chemistry;96 %Chromat.
1,1,1,3',3',3'-hexafluoro-propanol
920-66-1

1,1,1,3',3',3'-hexafluoro-propanol

1-(4-(dichloro-λ3-iodanyl)phenyl)ethan-1-one
92527-07-6

1-(4-(dichloro-λ3-iodanyl)phenyl)ethan-1-one

A

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

B

Hexafluoroacetone
684-16-2

Hexafluoroacetone

Conditions
ConditionsYield
In dichloromethane-d2 at 20℃; for 20h; Inert atmosphere;A 65%
B n/a
4-(2-methyl-[1,3]dioxolan-2-yl)-phenylamine
19073-16-6

4-(2-methyl-[1,3]dioxolan-2-yl)-phenylamine

A

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

B

4-Aminoacetophenone
99-92-3

4-Aminoacetophenone

Conditions
ConditionsYield
With N-iodo-succinimide; sodium nitrite In N,N-dimethyl-formamide at 20℃; for 4h;A 31%
B 62%
4-acetyl-benzoic acid
586-89-0

4-acetyl-benzoic acid

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); 1-iodo-butane; N,N,N',N'-tetramethyl-1,8-diaminonaphthalene; chloro-N,N,N',N'-bis(tetramethylene)formamidinium hexafluorophosphate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In toluene at 120℃; for 16h; Sealed tube; Inert atmosphere;62%
potassium 4-acetylphenyltrifluoroborate

potassium 4-acetylphenyltrifluoroborate

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

Conditions
ConditionsYield
With chloroamine-T; sodium iodide In tetrahydrofuran; water at 20℃; for 1.5h;60%
α-(benzoyloxy)-p-iodoacetophenone
135774-36-6

α-(benzoyloxy)-p-iodoacetophenone

A

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

B

phenacyl benzoate
33868-50-7

phenacyl benzoate

Conditions
ConditionsYield
With 1,3-dimethyl-2-phenyl-2,3-dihydro-1H-benzo[d]imidazole; azobisisobutyronitrile In acetonitrile at 61℃; for 19h; Rate constant;A 19.6%
B 35%
1-(4-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)phenyl)ethan-1-one
460088-33-9

1-(4-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)phenyl)ethan-1-one

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

Conditions
ConditionsYield
With chloroamine-T; sodium iodide In tetrahydrofuran for 6h;30%
iodobenzene
591-50-4

iodobenzene

acetyl chloride
75-36-5

acetyl chloride

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

Conditions
ConditionsYield
With carbon disulfide; aluminium trichloride
With aluminium trichloride
With aluminum (III) chloride In dichloromethane at 40℃; for 24h; Friedel-Crafts Acylation; Sealed tube; Inert atmosphere;
methyllithium
917-54-4

methyllithium

4-iodobenzoic acid chloride
1711-02-0

4-iodobenzoic acid chloride

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

Conditions
ConditionsYield
(i) CuI, Et2O, (ii) /BRN= 774718/, MeOH; Multistep reaction;
iodobenzene
591-50-4

iodobenzene

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

2-bromo-1-(4-iodophenyl)ethanone
31827-94-8

2-bromo-1-(4-iodophenyl)ethanone

Conditions
ConditionsYield
With bromine In 1,4-dioxane at 20℃; for 1h;100%
With bromine In 1,4-dioxane at 0 - 20℃; for 1 - 1.66667h; Product distribution / selectivity;100%
With bromine In chloroform at 20℃; for 4h;94%
4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

(E)-1-(4-iodophenyl)-3-(4-methoxyphenyl)prop-2-en-1-one
92855-02-2

(E)-1-(4-iodophenyl)-3-(4-methoxyphenyl)prop-2-en-1-one

Conditions
ConditionsYield
With potassium hydroxide In ethanol; water at 20℃; for 4.25h; Cooling with ice;100%
With sodium hydroxide In methanol at 0 - 20℃; for 4h; Claisen-Schmidt condensation;91%
With SiO2-H3PO4 Aldol Condensation; Microwave irradiation;88%
4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

1-(4-iodophenyl)ethanol
68120-56-9, 104013-25-4, 53207-29-7

1-(4-iodophenyl)ethanol

Conditions
ConditionsYield
With zirconium dioxide hydrate; isopropyl alcohol at 130℃; for 0.366667h; Meerwein-Ponndorf-Verley Reduction;100%
With C9H8BrMnN2O3; potassium tert-butylate In isopropyl alcohol at 30℃; for 168h; Inert atmosphere; Schlenk technique; Glovebox;99%
With sodium tetrahydroborate In ethanol for 5h;98.7%
4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

acetophenone
98-86-2

acetophenone

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; cesium fluoride In 2-pentanol at 100℃; for 36h; Inert atmosphere;100%
With triethylamine In toluene at 20℃; for 24h; Inert atmosphere; Irradiation; Sealed tube;83.4%
With tris-(trimethylsilyl)silane In acetonitrile Schlenk technique; Inert atmosphere; Irradiation;80%
4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

phenylacetylene
536-74-3

phenylacetylene

4-(phenylethinyl)acetophenone
1942-31-0

4-(phenylethinyl)acetophenone

Conditions
ConditionsYield
With tetrabutylammonium acetate; copper aluminum In N,N-dimethyl-formamide at 110℃; for 24h; Sonogashira coupling;100%
With copper(l) iodide; triethylamine; triphenylphosphine In water at 60℃; for 24h; Sonogashira Cross-Coupling; Schlenk technique; Inert atmosphere;100%
With sodium phosphate dodecahydrate In water; isopropyl alcohol at 80℃; for 1h; Reagent/catalyst; Sonogashira Cross-Coupling; Inert atmosphere;100%
4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

methyl (2E)-3-(4-acetylphenyl)acrylate
71348-24-8, 71348-27-1

methyl (2E)-3-(4-acetylphenyl)acrylate

Conditions
ConditionsYield
With PdCl2[4,4'-bis(n-C10F21CH2OCH2)-2,2'-bipyridine]; triethylamine In N,N-dimethyl-formamide at 145℃; for 0.167h; Catalytic behavior; Reagent/catalyst; Heck Reaction; Microwave irradiation;100%
With trihexyl(tetradecyl)phosphonium chloride; sodium acetate; palladium diacetate In water at 50℃; for 2h; Heck reaction;99%
With C42H50Cl2N6Pd; sodium formate; triethylamine In N,N-dimethyl-formamide at 80℃; Heck Reaction; diastereospecific reaction;99%
4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

tetrabutylammonium triphenyldifluorosilicate

tetrabutylammonium triphenyldifluorosilicate

biphenyl-4-acetaldehyde
92-91-1

biphenyl-4-acetaldehyde

Conditions
ConditionsYield
bis(η3-allyl-μ-chloropalladium(II)) In N,N-dimethyl-formamide at 95℃; for 21h;100%
4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

(R)-(+)-1-(4-iodophenyl)ethanol
220089-24-7

(R)-(+)-1-(4-iodophenyl)ethanol

Conditions
ConditionsYield
With magnesium chloride In isopropyl alcohol at 25℃; pH=7; Catalytic behavior;100%
With (S,S)-RuCl2(2,2'-bis(di-3,5-xylylphosphino)-1,1'-binaphthyl)(1,1-dianisyl-2-isopropyl-1,2-ethylenediamine); potassium tert-butylate; hydrogen In isopropyl alcohol at 26 - 30℃; under 6080 Torr; for 4h;99.7%
With C37H40MnN2O2P2(1+)*Br(1-); sodium t-butanolate In isopropyl alcohol at 50℃; for 3h; Inert atmosphere; Schlenk technique; enantioselective reaction;98%
4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

(E)-2-pyridyldimethyl-(2-thien-2-ylethenyl)silane
321155-45-7

(E)-2-pyridyldimethyl-(2-thien-2-ylethenyl)silane

(E)-1-(4-acetyl)phenyl-2-(2-thienyl)ethene
63483-65-8

(E)-1-(4-acetyl)phenyl-2-(2-thienyl)ethene

Conditions
ConditionsYield
With bis(benzonitrile)palladium(II) dichloride; tetrabutyl ammonium fluoride In tetrahydrofuran at 60℃; Hiyama coupling;100%
acrylic acid n-butyl ester
141-32-2

acrylic acid n-butyl ester

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

(E)-3-(4-acetylphenyl)acrylic acid butyl ester
173464-57-8

(E)-3-(4-acetylphenyl)acrylic acid butyl ester

Conditions
ConditionsYield
With C29H33Cl2N5Pd; tetrabutylammomium bromide; sodium carbonate In N,N-dimethyl acetamide at 140℃; for 3h; Heck reaction; Inert atmosphere;100%
With tributyl-amine; chloro-[2-(9-phenyl-1,10-phenanthrolin-2-yl)phenyl]palladium In 1-methyl-pyrrolidin-2-one at 140℃; for 15h; Heck Reaction; Inert atmosphere;100%
With phenyl carbamate; potassium carbonate; palladium diacetate In N,N-dimethyl-formamide at 130℃; for 2h; Heck-type reaction;99%
4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

2-Methoxyphenylboronic acid
5720-06-9

2-Methoxyphenylboronic acid

4-acetyl-2'-methoxybiphenyl
52807-17-7

4-acetyl-2'-methoxybiphenyl

Conditions
ConditionsYield
With trihexyl(tetradecyl)phosphonium chloride; potassium phosphate; tris(dibenzylideneacetone)dipalladium(0) chloroform complex In toluene at 50℃; for 1h; Suzuki cross-coupling;100%
With caesium carbonate; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran Suzuki cross-coupling reaction; Heating;
4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

phenylboronic acid
98-80-6

phenylboronic acid

biphenyl-4-acetaldehyde
92-91-1

biphenyl-4-acetaldehyde

Conditions
ConditionsYield
With trihexyl(tetradecyl)phosphonium chloride; potassium phosphate; tris(dibenzylideneacetone)dipalladium(0) chloroform complex In toluene at 50℃; for 1h; Suzuki cross-coupling;100%
Stage #1: 4-Iodoacetophenone With tetrakis(triphenylphosphine) palladium(0) In 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide at 20 - 110℃; Suzuki coupling; Inert atmosphere; Ionic liquid;
Stage #2: phenylboronic acid With triethylamine In 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide; water at 20 - 110℃; Suzuki coupling; Ionic liquid; Inert atmosphere;
100%
With potassium carbonate In ethanol; water at 20℃; for 0.5h; Suzuki-Miyaura reaction; in air;100%
4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

2-methyl-but-3-yn-2-ol
115-19-5

2-methyl-but-3-yn-2-ol

1-(4-acetylphenyl)-3-methyl-1-butyn-3-ol
95785-28-7

1-(4-acetylphenyl)-3-methyl-1-butyn-3-ol

Conditions
ConditionsYield
With copper(l) iodide; 1-isobutyl-2,2,6,6-tetramethyl-phosphorinane*HBF4; diisopropylamine; bis(benzonitrile)palladium(II) dichloride In 1,4-dioxane at 20℃; for 6h; Sonogashira reaction;100%
With piperidine; copper(l) iodide; polystyrene-N(CH2PPh2)2PdCl2 In 1,4-dioxane at 60℃; for 2h; Sonogashira coupling reaction;94%
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine at 20℃; Inert atmosphere;90%
4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

4-Ethynylaniline
14235-81-5

4-Ethynylaniline

4-((4-aminophenyl)ethynyl)acetophenone
123770-68-3

4-((4-aminophenyl)ethynyl)acetophenone

Conditions
ConditionsYield
With triethylamine In water at 80℃; for 0.5h; Sonogashira Cross-Coupling;100%
With triethylamine; Nd2.04Cu0.95Pd0.05O4 In N,N-dimethyl-formamide at 120℃; for 16h; Sonogashira reaction;92%
With Pd/SiO2; triethylamine In diethyl ether; water at 20℃; for 10h; Sonogashira Cross-Coupling;86%
4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

4-Hydroxyacetophenone
99-93-4

4-Hydroxyacetophenone

Conditions
ConditionsYield
With sodium hydroxide; copper(l) iodide; L-proline In water at 20 - 300℃; microwave irradiation;100%
Stage #1: 4-Iodoacetophenone With copper(l) iodide; tetra(n-butyl)ammonium hydroxide In water at 60℃; for 24h; Inert atmosphere; Sealed tube;
Stage #2: With hydrogenchloride In water; ethyl acetate at 20℃; for 2h; Inert atmosphere; chemoselective reaction;
96%
With copper(l) iodide; potassium hydroxide In water at 100℃; Inert atmosphere;96%
N,N,N,N,-tetramethylethylenediamine
110-18-9

N,N,N,N,-tetramethylethylenediamine

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

bis(dibenzylideneacetone)-palladium(0)
32005-36-0

bis(dibenzylideneacetone)-palladium(0)

PdI(4-MeCOC6H4)(N,N,N',N'-tetramethylethylenediamine)
191667-17-1

PdI(4-MeCOC6H4)(N,N,N',N'-tetramethylethylenediamine)

Conditions
ConditionsYield
In not given byproducts: dibenzylideneacetone; N2-atmosphere; according to Markies, A. J. et al.: J. Organomet. Chem. 482 (1994) 191; elem. anal.;100%
tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

(E)-tert-butyl 3-(4-acetylphenyl)prop-2-enoate
389091-50-3

(E)-tert-butyl 3-(4-acetylphenyl)prop-2-enoate

Conditions
ConditionsYield
With tetrabutyl ammonium fluoride; palladium dichloride at 40℃; for 3h; Heck reaction; Inert atmosphere; neat (no solvent);100%
With tributyl-amine In N,N-dimethyl-formamide at 120℃; Heck-Mizoroki reaction;99%
With di-μ-iodobis(tri-tert-butylphosphino)dipalladium(l); N-ethyl-N,N-diisopropylamine In toluene at 100℃; for 15h; Heck Reaction; Inert atmosphere; Sealed tube; Glovebox;99%
4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

methyl 4-acetylcinnamate

methyl 4-acetylcinnamate

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 120℃; for 0.25h; Heck Reaction;100%
With triethylamine In water; acetonitrile at 120℃; for 3h; Heck Reaction; Green chemistry;99%
With 3C22H14N3O2(1-)*Ho(3+)*Pd(2+)*2Cl(1-); potassium carbonate In N,N-dimethyl-formamide at 100℃; for 1h; Heck Reaction;99%
(4-methylphenyl)gold(triphenylphosphine)
40667-81-0

(4-methylphenyl)gold(triphenylphosphine)

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

1-{4-[2-(4-methylphenyl)ethynyl]phenyl}ethanone
123770-66-1

1-{4-[2-(4-methylphenyl)ethynyl]phenyl}ethanone

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; diisopropylamine; 1,2-bis-(diphenylphosphino)ethane In toluene at 130℃; for 16h; Sonogashira coupling; Inert atmosphere;100%
4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

4,4-dimethyl-1-phenyl-1-(pyridin-2-yl)pent-2-yn-1-ol
1046337-99-8

4,4-dimethyl-1-phenyl-1-(pyridin-2-yl)pent-2-yn-1-ol

2-(4-acetylphenyl)-3-tert-butyl-8a-phenylindolizin-1(8aH)-one
1227746-69-1

2-(4-acetylphenyl)-3-tert-butyl-8a-phenylindolizin-1(8aH)-one

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In acetonitrile at 90℃; for 13h;100%
4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

3-phenyl-1,1-di(pyridin-2-yl)prop-2-yn-1-ol
87446-01-3

3-phenyl-1,1-di(pyridin-2-yl)prop-2-yn-1-ol

2-(4-acetylphenyl)-3-phenyl-8a-(pyridin-2-yl)indolizin-1(8aH)-one
1383711-44-1

2-(4-acetylphenyl)-3-phenyl-8a-(pyridin-2-yl)indolizin-1(8aH)-one

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In acetonitrile at 90℃; for 13h;100%
4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

1-(4-iodophenyl)ethan-1-one oxime
27760-43-6

1-(4-iodophenyl)ethan-1-one oxime

Conditions
ConditionsYield
With hydroxylamine hydrochloride; sodium acetate In ethanol; water at 95℃;100%
With hydroxylamine hydrochloride; sodium hydroxide In methanol at 20℃; Green chemistry;78%
With hydroxylamine hydrochloride; sodium acetate In ethanol; water for 1h; Reflux;
4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

m-tolylboronic acid
17933-03-8

m-tolylboronic acid

4-acetyl-3'-methylbiphenyl
76650-29-8

4-acetyl-3'-methylbiphenyl

Conditions
ConditionsYield
With potassium carbonate In water; N,N-dimethyl-formamide at 80℃; for 0.333333h; Suzuki-Miyaura Coupling; Green chemistry;100%
With potassium carbonate In water at 25℃; for 2h; Suzuki Coupling; Schlenk technique;98%
With potassium carbonate In water at 20℃; for 4h; Catalytic behavior; Suzuki-Miyaura Coupling;100 %Chromat.
4,7-dichloroisatin
18711-13-2

4,7-dichloroisatin

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

4,7-dichloro-3-hydroxyl-3-[2-(4-iodophenyl-2-oxoethyl)]-1,3-dihydroindol-2-one
1037184-42-1

4,7-dichloro-3-hydroxyl-3-[2-(4-iodophenyl-2-oxoethyl)]-1,3-dihydroindol-2-one

Conditions
ConditionsYield
With diethylamine In methanol at 20℃;100%
4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

2-(2-(4-bromophenyl)-4-(4-ethylphenyl)-5-(4-methoxyphenyl)furan-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2-(2-(4-bromophenyl)-4-(4-ethylphenyl)-5-(4-methoxyphenyl)furan-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

1-(4-(2-(4-bromophenyl)-4-(4-ethylphenyl)-5-(4-methoxyphenyl)furan-3-yl)phenyl)ethan-1-one

1-(4-(2-(4-bromophenyl)-4-(4-ethylphenyl)-5-(4-methoxyphenyl)furan-3-yl)phenyl)ethan-1-one

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium hydroxide In tetrahydrofuran at 20℃; for 12h; Inert atmosphere; Schlenk technique;100%
4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

4,4'-diacetylbiphenyl
787-69-9

4,4'-diacetylbiphenyl

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine; [2-(Pd-Cl)-4,4'-dichlorobenzophenone oxime]2 In decane; N,N-dimethyl-formamide at 110℃; for 5h; Ullmann homocoupling;99%
With potassium iodide; nickel dibromide; zinc In N,N,N,N,N,N-hexamethylphosphoric triamide; N,N-dimethyl-formamide at 50℃; for 3h;98%
With potassium phosphate In water at 110℃; for 48h; Ullmann Condensation;98%
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

2-(4-iodophenyl)-2-hexanol
84735-52-4

2-(4-iodophenyl)-2-hexanol

Conditions
ConditionsYield
With cerium(III) triiodide In tetrahydrofuran; hexane at -65℃; for 3h;99%
Stage #1: n-butyllithium With cerium(III) chloride at -78℃;
Stage #2: 4-Iodoacetophenone at -78℃;
93%
With cerium(III) triiodide in THF, 1) -65 deg C, 30 min., 2) -65 deg C, 3h; Yield given. Multistep reaction;
ethanol
64-17-5

ethanol

4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

carbon monoxide
201230-82-2

carbon monoxide

ethyl-4-acetylbenzoate
38430-55-6

ethyl-4-acetylbenzoate

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene; palladium diacetate at 20 - 125℃; under 7500.75 - 22502.3 Torr; for 0.333333h; microwave irradiation;99%
With 1,8-diazabicyclo[5.4.0]undec-7-ene; palladium diacetate at 125℃; under 7757.43 Torr; for 0.333333h; microwave irradiation;97%
With triethylamine at 100℃; under 3750.38 Torr; for 1.5h; Inert atmosphere;96%
4-Iodoacetophenone
13329-40-3

4-Iodoacetophenone

acrylic acid
79-10-7

acrylic acid

4-acetylcinnamic acid
18910-24-2

4-acetylcinnamic acid

Conditions
ConditionsYield
With potassium hydroxide In water at 90℃; for 5h; Mizoroki-Heck reaction;99%
With potassium hydroxide In methanol at 80℃; for 24h; Heck reaction;65%
With sodium carbonate; palladium dichloride In water at 100℃; Yield given;
With palladium diacetate; potassium carbonate In water at 120℃; for 0.416667h; Heck reaction; Microwave irradiation;
With potassium carbonate In water at 90℃; for 12h; Heck Reaction; Inert atmosphere;

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