122183-72-6Relevant academic research and scientific papers
The stereoselective Horner-Wittig reaction with phoshine oxides: Synthesis of hindered Z alkenes via Luche reduction
Hutton,Jolliff,Mitchell,Warren
, p. 7905 - 7908 (2007/10/02)
The natural anti selectivity of the Horner-Wittig reaction with phospine oxides is reduced when there is a branched chain next to the new C=C double bond. A better approach is Luche reduction of the corresponding ketones which gives high anti selectivity when the branched chain is placed on the side chain next to the phosphine oxide.
