122212-34-4

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 583-75-5 4-Bromo-2-methylaniline 

Downstream Products

• 126742-81-2 2-(4-Bromo-2-bromomethyl-phenyl)-1,1,1,3,3,3-hexamethyl-disilazane 
• 83515-06-4 5-bromo-2-phenylindole 
• 671792-39-5 2-[2-amino-5-(3-methyl-but-2-enyl)-phenyl]-1-[8-hydroxymethyl-6a,7-dimethyl-3-(1-methyl-1-triethylsilanyloxy-ethyl)-2-triethylsilanyloxy-2,3,4a,5,6,6a,7,8,9,10-decahydro-1H-benzo[f]chromen-7-yl]-ethanone 
• 502614-05-3 (-)-{(2R,3S,4aS,6aR,7S,10aS,11aR)-3-[1-(benzyloxy)-1-methylethyl]-2,3,4a,5,6,6a,7,8,9,10-decahydro-6a,7-dimethyl-7-[5-(3-methylbut-2-enyl)-1H-indol-2-yl]-2-[(triethylsilyl)oxy]-1H-benzo[f]oxireno[2,3-e][1]benzopyran-8-yl}methyl metanesulfonate 
• 502614-06-4 (-)-(2S,3R,4aR,5aS,13bS,13cR,15aS)-2-[1-(benzyloxy)-1-methylethyl]-3,4,5,6,7,7a,8,13,13b,13c,14,15,15a-dodecahydro-13b,13c-dimethyl-10-(3-methylbut-2-enyl)-3-[(triethylsilyl)oxy]-2H-oxireno[2'',3'':4a',5'][1]benzopyrano[5'6':6,7]indeno[1,2-b]indole 
• 502614-04-2 (-)-{(2R,3S,4aS,6aR,7S,10aS,11aR)-3-[(1-(benzyloxy)-1-methylethyl]-2,3,4a,5,6,6a,7,8,9,10-decahydro-6a,7-dimethyl-7-[5-3-methylbut-2-enyl)-1H-indol-2-yl]-2-[(triethylsilyl)oxy]-1H-benzo[f]oxireno[2,3-e][1]benzopyran-8-yl}methanol 
• 502614-07-5 (-)-(2S,3R,4aR,5aS,13bS,13cR,15aS)-2-[1-(benzyloxy)-1-methylethyl]-3,4,5,6,7,7a,8,13,13b,13c,14,15,15a-dodecahydro-13b,13c-dimethyl-10-(3-methylbut-2-enyl)-2H-oxireno[2'',3'':4a',5'][1]benzopyrano[5'6':6,7]indeno[1,2-b]indol-3-ol 
• 502614-08-6 (+)-(2R,4bS,12bS,12cR,14aS)-2-[1-(benzyloxy)-1-methylethyl]-5,6,6a,7,12,12b,12c,13,14,14a-decahydro-4b-hydroxy-12b,12c-dimethyl-9-(3-methylbut-2-enyl)-2H-[1]benzopyrano[5'6':6,7]indeno[1,2-b]indol-3(4bH)-one 
• 502613-88-9 2-methyl-4-(3-methylbut-2-enyl)benzeneamine 

Relevant academic research and scientific papers

Total synthesis of (-)-21-isopentenylpaxilline.

[structure: see text] The total synthesis of (-)-21-isopentenylpaxilline (1) has been achieved. Key elements of the synthesis include the stereocontrolled construction of the advanced eastern hemisphere (-)-5, a highly efficient union of the eastern and w

Indole-Diterpene Synthetic Studies: Total Synthesis of (-)-21-Isopentenylpaxilline

An efficient, stereocontrolled total synthesis of the complex indole-diterpene alkaloid (-)-21-isopentenylpaxilline (1) has been achieved. Key elements of the synthesis include the stereocontrolled construction of the advanced eastern hemisphere (-)-68, i

Mixed Copper, Zinc 2-Amino Benzylic Organometallics as Efficient Reagents for the Synthesis of Heterocycles

The mixed copper, zinc benzylic organometallics 1a-1c react efficiently with various electrophiles.By the reaction with acylchlorides, highly functionalized 2-substituted indoles are produced.The treatment of 1a with allylic bromides, 3-iodo-cyclohexenone and ethyl propiolate furnishes polyfunctionalized anilines.Several of them could be converted into five or seven-membered heterocycles.