1222190-50-2

Upstream product

• 122606-77-3 (R)-4-hydroxy-1-undecene 
• 100-52-7 benzaldehyde 
• 124-13-0 Octanal 
• 1222190-44-4 2-((2R,4R,6R)-6-heptyl-2-phenyl-1,3-dioxan-4-yl)-N-methoxy-N-methylacetamide 
• 1222190-46-6 (R,E)-5-hydroxy-N-methoxy-N-methyldodec-2-enamide 
• 1222190-45-5 (R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-3-hydroxydecan-1-one 
• 1222190-43-3 (S)-1-((2R,4S,6R)-6-heptyl-2-phenyl-1,3-dioxan-4-yl)pent-4-en-2-ol 
• 1222190-49-9 1-[(2R,4R,6R)-6-heptyl-2-phenyl-1,3-dioxan-4-yl]pent-4-en-2-one 
• 124931-12-0 diethyl (N-methoxy-N-methylcarbamoylmethyl)phosphonate 

Downstream Products

• 1222190-51-3 2-[(2R,4R,6R)-6-{[(2R,4R,6R)-6-heptyl-2-phenyl-1,3-dioxan-4-yl]methyl}-2-phenyl-1,3-dioxan-4-yl]-N-methoxy-N-methylacetamide 
• 1222190-41-1 2-[(2R,4R,6R)-6-{[(2R,4R,6R)-6-heptyl-2-phenyl-1,3-dioxan-4-yl]methyl}-2-phenyl-1,3-dioxan-4-yl]acetaldehyde 
• 1353031-23-8 ethyl (Z)-4-[(2S,4S,6S)-6-{[(2R,4R,6R)-6-heptyl-2-phenyl-1,3-dioxan-4-yl]methyl}-2-phenyl-1,3-dioxan-4-yl]but-2-enoate 
• 1353031-43-2 1-[(2R,4R,6R)-6-{[(2R,4R,6R)-6-Heptyl-2-phenyl-1,3-dioxan-4-yl]methyl}-2-phenyl-1,3-dioxan-4-yl]pent-4-en-2-one 
• 1353031-25-0 (S)-1-[(2S,4S,6S)-6-{[(2R,4R,6R)-6-heptyl-2-phenyl-1,3-dioxan-4-yl]methyl}-2-phenyl-1,3-dioxan-4-yl]pent-4-en-2-ol 
• 1353031-45-4 C₃₆H₄₈O₆ 
• 1353031-47-6 (S)-6-{[(2R,4R,6S)-6-{[(2R,4R,6R)-6-heptyl-2-phenyl-1,3-dioxan-4-yl]methyl}-2-phenyl-1,3-dioxan-4-yl]methyl}-5,6-dihydropyran-2-one 

Relevant academic research and scientific papers

Stereoselective total synthesis of polyrhacitides A and B

Two aliphatic polyketide natural products, polyrhacitides A and B, have been synthesized in a concise and highly stereoselective manner. The synthesis involved an auxiliary-based acetate aldol reaction to generate the initial stereogenic center and an ite

Stereoselective total synthesis of (+)-polyrhacitide A

A facile stereoselective total synthesis of secondary metabolite (+)-polyrhacitide A is described. Stereoselective aldol reaction, Horner-Wardsworth-Emmons reaction, Evans acetal intramolecular oxa-Michael reaction and diastereoselective syn reduction reaction are the key steps involved in the target synthesis.